Acetamide, N-[2-[(2-bromo-4,6-dinitrophenyl)azo]-5-(diethylamino)phenyl]-

Base Information

• Chemical Name: Acetamide, N-[2-[(2-bromo-4,6-dinitrophenyl)azo]-5-(diethylamino)phenyl]-
• CAS No.: 52697-38-8
• Molecular Formula: C18H19 Br N6 O5
• Molecular Weight: 479.29
• Hs Code.: 2927000090
• European Community (EC) Number: 258-110-1
• DSSTox Substance ID: DTXSID5068784
• Nikkaji Number: J38.094F
• Mol file: 52697-38-8.mol

Synonyms:52697-38-8;Disperse Violet 93;Acetamide, N-[2-[(2-bromo-4,6-dinitrophenyl)azo]-5-(diethylamino)phenyl]-;EINECS 258-110-1;C.I. Disperse violet 93;N-[2-[(2-Bromo-4,6-dinitrophenyl)azo]-5-(diethylamino)phenyl]acetamide;N-[2-[(2-bromo-4,6-dinitrophenyl)diazenyl]-5-(diethylamino)phenyl]acetamide;2'-((2-Bromo-4,6-dinitrophenyl)azo)-5'-diethylamino)acetanilide;Acetanilide, 2-(2,4-dinitro-6-bromophenylazo)-5-N,N-diethylamino-;2-Bromo-4,6-dinitro-1-((2-(acetylamino)-4-(diethylamino)phenyl)azo)benzene;Acetamide, N-(2-((2-bromo-4,6-dinitrophenyl)azo)-5-(diethylamino)phenyl)-;Acetamide,N-[2-[(2-bromo-4,6-dinitrophenyl)azo]-5-(diethylamino)phenyl]-;N-(2-((2-Bromo-4,6-dinitrophenyl)azo)-5-(diethylamino)phenyl)acetamide;Acetamide, N-(2-(2-(2-bromo-4,6-dinitrophenyl)diazenyl)-5-(diethylamino)phenyl)-;C.I.Disperse Violet 93;C18H19BrN6O5;SCHEMBL9004922;DTXSID5068784;SCHEMBL13474917;C18-H19-Br-N6-O5;FT-0707247;W-111055;2-Bromo-4,6-dinitro-2'-acetylamino-4'-(N,N-diethylamino)azobenzene;3-acetamido-4-(2'bromo-4',6'-dinitrophenylazo)-N,N-diethylaniline;3-acetamido-4-(2'bromo-4',6'-dinitrophenylazo)N,N-diethylaniline;2-Bromo-4,6-dinitro-2'-acetylamino-4'-(N,N-diethylamino) azobenzene;3-acetylamino-4-(2'-bromo-4',6'-dinitrophenylazo)-N,N-diethylaniline;Acetamide, N-[2-[(2-bromo-4,6-dinitrophenyl) azo]-5-(diethylamino)phenyl]-;N-[2-[(E)-(2-bromo-4,6-dinitrophenyl)diazenyl]-5-(diethylamino)phenyl]acetamide

Chemical Property of Acetamide, N-[2-[(2-bromo-4,6-dinitrophenyl)azo]-5-(diethylamino)phenyl]-

Chemical Property:

• Vapor Pressure: 3.54E-19mmHg at 25°C
• Melting Point: 184-186 °C
• Boiling Point: 695.2°Cat760mmHg
• PKA: 14.02±0.70(Predicted)
• Flash Point: 374.3°C
• PSA: 148.70000
• Density: 1.55g/cm³
• LogP: 6.60490
• Water Solubility.: 20μg/L at 20℃
• XLogP3: 4.1
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 8
• Rotatable Bond Count: 6
• Exact Mass: 478.06003
• Heavy Atom Count: 30
• Complexity: 650

Purity/Quality:

99.9% ^*data from raw suppliers

N-[2-[(2-Bromo-4,6-dinitrophenyl)azo]-5-(diethylamino)phenyl]acetamide ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCN(CC)C1=CC(=C(C=C1)N=NC2=C(C=C(C=C2Br)[N+](=O)[O-])[N+](=O)[O-])NC(=O)C
• Uses: Disperse Violet 93 is a disperse dye. Dyes and metabolites, Environmental Testing.

Technology Process of Acetamide, N-[2-[(2-bromo-4,6-dinitrophenyl)azo]-5-(diethylamino)phenyl]-

There total 9 articles about Acetamide, N-[2-[(2-bromo-4,6-dinitrophenyl)azo]-5-(diethylamino)phenyl]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

N-(3-aminophenyl)-acetamide hydrochloride (621-35-2,59736-00-4) → 3-acetylamino-4-(2'-bromo-4',6'-dinitrophenylazo)-N,N-diethylaniline (52697-38-8)

Guidance literature:

Multi-step reaction with 3 steps

1: 20 percent NaCl-solution / pH

2: NaHCO₃ / H₂O / 8 h / 15 - 25 °C

3: 1) NaNO₂, conc. H₂SO₄; 2) amidosulfuric acid, HCl / 1) 2 h, r.t.; 2) water, 6 h

With hydrogenchloride; sulfuric acid; aminosulfonic acid; sodium hydrogencarbonate; sodium chloride; sodium nitrite; In water;

Reference yield:

m-phenylenediamine (108-45-2,64554-26-3,76583-20-5) → 3-acetylamino-4-(2'-bromo-4',6'-dinitrophenylazo)-N,N-diethylaniline (52697-38-8)

Guidance literature:

Multi-step reaction with 4 steps

1: HCl / H₂O / 8 h / pH = 1,5-3,5

2: 20 percent NaCl-solution / pH

3: NaHCO₃ / H₂O / 8 h / 15 - 25 °C

4: 1) NaNO₂, conc. H₂SO₄; 2) amidosulfuric acid, HCl / 1) 2 h, r.t.; 2) water, 6 h

With hydrogenchloride; sulfuric acid; aminosulfonic acid; sodium hydrogencarbonate; sodium chloride; sodium nitrite; In water;

Reference yield:

m-acetamide aniline (102-28-3) → 3-acetylamino-4-(2'-bromo-4',6'-dinitrophenylazo)-N,N-diethylaniline (52697-38-8)

Guidance literature:

Multi-step reaction with 2 steps

1: NaHCO₃ / H₂O / 8 h / 15 - 25 °C

2: 1) NaNO₂, conc. H₂SO₄; 2) amidosulfuric acid, HCl / 1) 2 h, r.t.; 2) water, 6 h

With hydrogenchloride; sulfuric acid; aminosulfonic acid; sodium hydrogencarbonate; sodium nitrite; In water;

upstream raw materials:

nitrosylsulfuric acid

m-acetylamino-N,N-diethylanilne

2-bromo-4,6-dinitroaniline

3-(N,N-diethylamino)-6-aminoacetanilide

Downstream raw materials:

3-acetylamino-4-(2'-cyano-4',6'-dinitrophenylazo)-N,N-diethylaniline

2'-acetamido-4'-diethylamino-2,4-dinitroazobenzene

2-acetamido-4-diethylamino-6-diethylphosphonato-2',4'-dinitroazobenzene

N-{2-[2'-(2-Acetylamino-4-diethylamino-phenylazo)-3,5,3',5'-tetranitro-biphenyl-2-ylazo]-5-diethylamino-phenyl}-acetamide

Refernces

• 1、 -. "Disperse dye composition, and preparation method and application thereof". Paragraph 0102-0104; 0106. . Retrieved 2017/08/28.
• 2、 -. "Azo disperse dye mixtures". Example 6. . Retrieved 2010/11/30.