2-(4-methylthiophenyl)-4-(2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-henicosafluorodecyl)-[1,3,2]dioxaborolane

Base Information

• Chemical Name: 2-(4-methylthiophenyl)-4-(2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-henicosafluorodecyl)-[1,3,2]dioxaborolane
• CAS No.: 884844-91-1
• Molecular Formula: C₂₀H₁₂BF₂₁O₂S
• Molecular Weight: 726.158
• Mol file: 884844-91-1.mol

Synonyms:2-(4-methylthiophenyl)-4-(2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-henicosafluorodecyl)-[1,3,2]dioxaborolane

Chemical Property of 2-(4-methylthiophenyl)-4-(2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-henicosafluorodecyl)-[1,3,2]dioxaborolane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-(4-methylthiophenyl)-4-(2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-henicosafluorodecyl)-[1,3,2]dioxaborolane

There total 4 articles about 2-(4-methylthiophenyl)-4-(2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-henicosafluorodecyl)-[1,3,2]dioxaborolane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

3-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,13-henicosafluorodecyl)-propane 1,2-diol (114834-29-6) + 3-methylthiophenylboronic acid (128312-11-8) → 2-(4-methylthiophenyl)-4-(2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-henicosafluorodecyl)-[1,3,2]dioxaborolane (884844-91-1)

Guidance literature:

In various solvent(s); at 70 ℃; for 15h;

DOI:10.1016/j.jfluchem.2004.12.014

Reference yield:

1-Iodo-perfluorodecane (423-62-1) → 2-(4-methylthiophenyl)-4-(2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-henicosafluorodecyl)-[1,3,2]dioxaborolane (884844-91-1)

Guidance literature:

Multi-step reaction with 4 steps

1: 86 percent / dibenzoyl peroxide / various solvent(s) / 8 h / 95 - 100 °C

2: 75 percent / Zn; AcOH / propan-2-ol / 7 h / Heating

3: 87 percent / aq. N-methylmorpholine-N-oxide; pyridine; OsO₄ / acetone / 21 h / 0 - 50 °C

4: 94 percent / various solvent(s) / 15 h / 70 °C

With pyridine; osmium(VIII) oxide; acetic acid; 4-methylmorpholine N-oxide; zinc; dibenzoyl peroxide; In isopropyl alcohol; acetone;

DOI:10.1016/j.jfluchem.2004.12.014

Reference yield:

2-iodo-3-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,13-henicosafluorodecyl)propyl acetate (40798-40-1) → 2-(4-methylthiophenyl)-4-(2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-henicosafluorodecyl)-[1,3,2]dioxaborolane (884844-91-1)

Guidance literature:

Multi-step reaction with 3 steps

1: 75 percent / Zn; AcOH / propan-2-ol / 7 h / Heating

2: 87 percent / aq. N-methylmorpholine-N-oxide; pyridine; OsO₄ / acetone / 21 h / 0 - 50 °C

3: 94 percent / various solvent(s) / 15 h / 70 °C

With pyridine; osmium(VIII) oxide; acetic acid; 4-methylmorpholine N-oxide; zinc; In isopropyl alcohol; acetone;

DOI:10.1016/j.jfluchem.2004.12.014

upstream raw materials:

3-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,13-henicosafluorodecyl)-propane 1,2-diol

3-methylthiophenylboronic acid

1-Iodo-perfluorodecane

3-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,13-henicosafluorodecyl)-propene

Downstream raw materials:

3-methylsulfanylbiphenyl