5,10,15,20-tetrakis(2',6'-dichloro-3'-sulfonatophenyl)porphyrin

Base Information

• Chemical Name: 5,10,15,20-tetrakis(2',6'-dichloro-3'-sulfonatophenyl)porphyrin
• CAS No.: 120644-24-8
• Molecular Formula: C₄₄H₂₂Cl₈N₄O₁₂S₄
• Molecular Weight: 1210.57
• Mol file: 120644-24-8.mol

Synonyms:5,10,15,20-tetrakis(2',6'-dichloro-3'-sulfonatophenyl)porphyrin

Chemical Property of 5,10,15,20-tetrakis(2',6'-dichloro-3'-sulfonatophenyl)porphyrin

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 5,10,15,20-tetrakis(2',6'-dichloro-3'-sulfonatophenyl)porphyrin

There total 5 articles about 5,10,15,20-tetrakis(2',6'-dichloro-3'-sulfonatophenyl)porphyrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

5,10,15,20-tetra(2,6-dichloro-3-chlorosulphonylphenyl)-21H,23H-porphyrin → 5,10,15,20-tetrakis(2',6'-dichloro-3'-sulfonatophenyl)porphyrin (120644-24-8)

Guidance literature:

With water; for 12h; Heating;

DOI:10.1016/j.tet.2008.03.055

Reference yield:

5,10,15,20-tetrakis(2,6-dichlorophenyl)porphyrin (37083-37-7) → 5,10,15,20-tetrakis(2',6'-dichloro-3'-sulfonatophenyl)porphyrin (120644-24-8)

Guidance literature:

With sulfuric acid; at 130 ℃;

DOI:10.1016/S0968-0896(99)00202-3

Reference yield:

2,6-dichlorobenzaldehyde (83-38-5) → 5,10,15,20-tetrakis(2',6'-dichloro-3'-sulfonatophenyl)porphyrin (120644-24-8)

Guidance literature:

Multi-step reaction with 4 steps

1: boron trifluoride diethyl etherate / dichloromethane / 20 °C / Inert atmosphere; Darkness

2: chloranil / dichloromethane / 20 °C / Reflux; Inert atmosphere; Darkness

3: chlorosulfonic acid / 3 h / 100 °C

4: water / Cooling

With chlorosulfonic acid; boron trifluoride diethyl etherate; water; chloranil; In dichloromethane;

DOI:10.3184/174751911X12983110046865

upstream raw materials:

5,10,15,20-tetrakis(2,6-dichlorophenyl)porphyrin

2-(2,6-dichlorophenyl)acetic acid

2,6-dichlorobenzaldehyde