methyl (E)-2,4-di(methoxymethoxy)-6-methyl-3-<3-methyl-6-<5-(2-methyl-1-propenyl)-3-furanyl>-2-hexenyl>-benzoate

Base Information

Chemical Name:methyl (E)-2,4-di(methoxymethoxy)-6-methyl-3-<3-methyl-6-<5-(2-methyl-1-propenyl)-3-furanyl>-2-hexenyl>-benzoate
CAS No.:118608-03-0
Molecular Formula:C₂₈H₃₈O₇
Molecular Weight:486.606
Hs Code.:

Synonyms:methyl (E)-2,4-di(methoxymethoxy)-6-methyl-3-<3-methyl-6-<5-(2-methyl-1-propenyl)-3-furanyl>-2-hexenyl>-benzoate

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Chemical Property of methyl (E)-2,4-di(methoxymethoxy)-6-methyl-3-<3-methyl-6-<5-(2-methyl-1-propenyl)-3-furanyl>-2-hexenyl>-benzoate

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Technology Process of methyl (E)-2,4-di(methoxymethoxy)-6-methyl-3-<3-methyl-6-<5-(2-methyl-1-propenyl)-3-furanyl>-2-hexenyl>-benzoate

There total 17 articles about methyl (E)-2,4-di(methoxymethoxy)-6-methyl-3-<3-methyl-6-<5-(2-methyl-1-propenyl)-3-furanyl>-2-hexenyl>-benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 24470-78-8
isopropyltriphenylphosphonium iodide

: 118608-02-9
methyl (E)-2,4-di(methoxymethoxy)-6-methyl-3-<3-methyl-6-(furanyl-5-carboxaldehyde)-2-hexenyl>-benzoate

: 118608-03-0
methyl (E)-2,4-di(methoxymethoxy)-6-methyl-3-<3-methyl-6-<5-(2-methyl-1-propenyl)-3-furanyl>-2-hexenyl>-benzoate

Guidance literature:: With n-butyllithium; 1.) THF, -78 deg C to 0 deg C, 20 min, 2.) THF, -78 deg C, 30 min, then 0 deg C, 30 min;
DOI:10.1016/S0040-4020(01)85090-0

Reference yield:

: 27065-51-6
2-(diethoxymethyl)-4-bromofuran

: 118608-03-0
methyl (E)-2,4-di(methoxymethoxy)-6-methyl-3-<3-methyl-6-<5-(2-methyl-1-propenyl)-3-furanyl>-2-hexenyl>-benzoate

Guidance literature:: Multi-step reaction with 2 steps

1: 47 percent / n-BuLi / tetrahydrofuran; hexamethylphosphoric acid triamide / Ambient temperature

2: 78 percent / 1.)BuLi / 1.) THF, -78 deg C to 0 deg C, 20 min, 2.) THF, -78 deg C, 30 min, then 0 deg C, 30 min

With n-butyllithium; In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide;
DOI:10.1016/S0040-4020(01)85090-0

Reference yield:

: 86864-59-7
5-((tert-butyldimethylsilyl)oxy)pentan-2-one

: 118608-03-0
methyl (E)-2,4-di(methoxymethoxy)-6-methyl-3-<3-methyl-6-<5-(2-methyl-1-propenyl)-3-furanyl>-2-hexenyl>-benzoate

Guidance literature:: Multi-step reaction with 10 steps

1: 17.25 g / NaH / tetrahydrofuran; hexane; diethyl ether / 40 h / Ambient temperature

2: 96 percent / DIBAL / CH₂Cl₂ / -78 deg C, 1 h, then 0 deg C

3: CBr₄, Ph₃P / CH₂Cl₂ / 1 h / -78 °C

4: 3.10 g / toluene / 12 h / Heating

5: 66 percent / NaH / CH₂Cl₂ / 1 h / Ambient temperature

6: 100 percent / tetrabutylammonium fluoride / tetrahydrofuran / 2 h

7: 100 percent / triethylamine / CH₂Cl₂ / 0.5 h / 0 °C

8: 94 percent / NaI / acetone / 4 h / 50 °C

9: 47 percent / n-BuLi / tetrahydrofuran; hexamethylphosphoric acid triamide / Ambient temperature

10: 78 percent / 1.)BuLi / 1.) THF, -78 deg C to 0 deg C, 20 min, 2.) THF, -78 deg C, 30 min, then 0 deg C, 30 min

With n-butyllithium; carbon tetrabromide; tetrabutyl ammonium fluoride; sodium hydride; diisobutylaluminium hydride; triethylamine; triphenylphosphine; sodium iodide; In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; diethyl ether; hexane; dichloromethane; acetone; toluene;
DOI:10.1016/S0040-4020(01)85090-0