(2S,3R,4S,5R)-2,4,5-Tris(benzoyloxy)-1,1-bis[(benzoyloxy)methyl]-3-{[(methylsulfanyl)thiocarbonyl]oxy}cyclohexane

Base Information

Chemical Name:(2S,3R,4S,5R)-2,4,5-Tris(benzoyloxy)-1,1-bis[(benzoyloxy)methyl]-3-{[(methylsulfanyl)thiocarbonyl]oxy}cyclohexane
CAS No.:360562-18-1
Molecular Formula:C₄₅H₃₈O₁₁S₂
Molecular Weight:818.922
Hs Code.:

Synonyms:(2S,3R,4S,5R)-2,4,5-Tris(benzoyloxy)-1,1-bis[(benzoyloxy)methyl]-3-{[(methylsulfanyl)thiocarbonyl]oxy}cyclohexane

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Chemical Property of (2S,3R,4S,5R)-2,4,5-Tris(benzoyloxy)-1,1-bis[(benzoyloxy)methyl]-3-{[(methylsulfanyl)thiocarbonyl]oxy}cyclohexane

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Technology Process of (2S,3R,4S,5R)-2,4,5-Tris(benzoyloxy)-1,1-bis[(benzoyloxy)methyl]-3-{[(methylsulfanyl)thiocarbonyl]oxy}cyclohexane

There total 7 articles about (2S,3R,4S,5R)-2,4,5-Tris(benzoyloxy)-1,1-bis[(benzoyloxy)methyl]-3-{[(methylsulfanyl)thiocarbonyl]oxy}cyclohexane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 75-15-0,12122-00-8
carbon disulfide

: 360562-17-0
(1R,2S,5R,6S)-2,5,6-Tris(benzoyloxy)-3,3-bis[(benzoyloxy)methyl]cyclohexan-1-ol

: 74-88-4
methyl iodide

: 360562-18-1
(2S,3R,4S,5R)-2,4,5-Tris(benzoyloxy)-1,1-bis[(benzoyloxy)methyl]-3-{[(methylsulfanyl)thiocarbonyl]oxy}cyclohexane

Guidance literature:: carbon disulfide; (1R,2S,5R,6S)-2,5,6-Tris(benzoyloxy)-3,3-bis[(benzoyloxy)methyl]cyclohexan-1-ol; With sodium hydride; In N,N-dimethyl-formamide; at 0 ℃; for 0.5h;

methyl iodide; In N,N-dimethyl-formamide; at 0 - 20 ℃; for 1h;
DOI:10.1135/cccc20010785

Reference yield:

: 98-88-4
benzoyl chloride

: 360562-18-1
(2S,3R,4S,5R)-2,4,5-Tris(benzoyloxy)-1,1-bis[(benzoyloxy)methyl]-3-{[(methylsulfanyl)thiocarbonyl]oxy}cyclohexane

Guidance literature:: Multi-step reaction with 3 steps

1.1: 93 percent / pyridine / 50 h / 20 °C

2.1: 91 percent / H₂ / 10 percent Pd/C / methanol; dimethylformamide / 45 h

3.1: NaH / dimethylformamide / 0.5 h / 0 °C

3.2: 90 percent / dimethylformamide / 1 h / 0 - 20 °C

With pyridine; hydrogen; sodium hydride; palladium on activated charcoal; In methanol; N,N-dimethyl-formamide;
DOI:10.1135/cccc20010785

Reference yield:

: 360562-15-8
(1R,2R,3R,4S)-3-(Benzyloxy)-5,5-bis(hydroxymethyl)cyclohexane-1,2,4-triol

: 360562-18-1
(2S,3R,4S,5R)-2,4,5-Tris(benzoyloxy)-1,1-bis[(benzoyloxy)methyl]-3-{[(methylsulfanyl)thiocarbonyl]oxy}cyclohexane

Guidance literature:: Multi-step reaction with 3 steps

1.1: 93 percent / pyridine / 50 h / 20 °C

2.1: 91 percent / H₂ / 10 percent Pd/C / methanol; dimethylformamide / 45 h

3.1: NaH / dimethylformamide / 0.5 h / 0 °C

3.2: 90 percent / dimethylformamide / 1 h / 0 - 20 °C

With pyridine; hydrogen; sodium hydride; palladium on activated charcoal; In methanol; N,N-dimethyl-formamide;
DOI:10.1135/cccc20010785