C₃₉H₅₆O₁₁Si

Base Information

• Chemical Name: C₃₉H₅₆O₁₁Si
• CAS No.: 1035113-18-8
• Molecular Formula: C₃₉H₅₆O₁₁Si
• Molecular Weight: 728.953
• Mol file: 1035113-18-8.mol

Synonyms:C₃₉H₅₆O₁₁Si

Chemical Property of C₃₉H₅₆O₁₁Si

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₃₉H₅₆O₁₁Si

There total 1 articles about C₃₉H₅₆O₁₁Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

tert-butyldimethylsilyl chloride (18162-48-6) + acetoxybrevifoliol (146621-74-1) → C39H56O11Si (1035113-18-8)

Guidance literature:

With 1H-imidazole; In N,N-dimethyl-formamide; at -40 ℃; for 10h; Inert atmosphere;

DOI:10.1021/jm400479p

Reference yield: 90.0%

C39H56O11Si (1035113-18-8) → C39H54O11Si (1035113-20-2)

Guidance literature:

With pyridinium chlorochromate; In dichloromethane; at 20 ℃; for 8h; Inert atmosphere;

DOI:10.1021/jm400479p

Reference yield:

C39H56O11Si (1035113-18-8) → C51H65NO16

Guidance literature:

Multi-step reaction with 3 steps

1.1: pyridinium chlorochromate / dichloromethane / 8 h / 20 °C / Inert atmosphere

2.1: hydrogen fluoride; pyridine / water; tetrahydrofuran / 2 h / 20 °C / Inert atmosphere

3.1: sodium hexamethyldisilazane / tetrahydrofuran / 0.5 h / -78 °C / Inert atmosphere

3.2: Inert atmosphere

With pyridine; hydrogen fluoride; sodium hexamethyldisilazane; pyridinium chlorochromate; In tetrahydrofuran; dichloromethane; water;

DOI:10.1021/jm400479p

upstream raw materials:

tert-butyldimethylsilyl chloride

acetoxybrevifoliol

Downstream raw materials:

C₃₉H₅₄O₁₁Si

C₃₃H₄₀O₁₁

C₃₁H₃₆O₉

C₄₇H₄₉NO₁₂

Refernces