[(η5-C5Me5)Fe(1,2-bis(diphenylphosphino)ethane)GaI][B(C6H3(CF3)-3,5)4]

Base Information

• Chemical Name: [(η5-C5Me5)Fe(1,2-bis(diphenylphosphino)ethane)GaI][B(C6H3(CF3)-3,5)4]
• CAS No.: 1021939-87-6
• Molecular Formula: C₃₂H₁₂BF₂₄*C₃₆H₃₉FeGaIP₂
• Molecular Weight: 1649.35
• Mol file: 1021939-87-6.mol

Synonyms:[(η5-C5Me5)Fe(1,2-bis(diphenylphosphino)ethane)GaI][B(C6H3(CF3)-3,5)4]

Chemical Property of [(η5-C5Me5)Fe(1,2-bis(diphenylphosphino)ethane)GaI][B(C6H3(CF3)-3,5)4]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(η5-C5Me5)Fe(1,2-bis(diphenylphosphino)ethane)GaI][B(C6H3(CF3)-3,5)4]

There total 1 articles about [(η5-C5Me5)Fe(1,2-bis(diphenylphosphino)ethane)GaI][B(C6H3(CF3)-3,5)4] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 35.0%

[(η5-C5Me5)Fe(1,2-bis(diphenylphosphino)ethane)GaI2]*1.25toluene + sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate (79060-88-1) → [(η5-C5Me5)Fe(1,2-bis(diphenylphosphino)ethane)GaI][B(C6H3(CF3)-3,5)4] (1021939-87-6)

Guidance literature:

In fluorobenzene; (inert atm.); addn. of soln. of iron compd. in fluorobenzene to suspn. of borate salt in fluorobenzene at -30°C, warming to 20°C for 20 min; filtration, concg., layering with hexanes, keeping at -30°C, isolation of crystals, NMR and MS;

DOI:10.1021/ja806655f

Reference yield:

[(η5-C5Me5)Fe(1,2-bis(diphenylphosphino)ethane)GaI][B(C6H3(CF3)-3,5)4] (1021939-87-6) + tetra-(n-butyl)ammonium iodide (311-28-4) → [(η5-C5Me5)Fe(1,2-bis(diphenylphosphino)ethane)GaI2]*1.25toluene

Guidance literature:

In further solvent(s); (inert atm.); treatment of fluorobenzene-d5 soln. of iron compd. with 1.2 equiv. of iodide salt in fluorobenzene-d5 at 20°C for 5 min; NMR monitoring;

DOI:10.1021/ja806655f

Reference yield:

carbon monoxide (201230-82-2) + [(η5-C5Me5)Fe(1,2-bis(diphenylphosphino)ethane)GaI][B(C6H3(CF3)-3,5)4] (1021939-87-6) → [Fe(η5-Cp*)(dppe)(CO)]BArF4 (1082448-70-1)

Guidance literature:

In further solvent(s); byproducts: Ga; (inert atm.); exposure of soln. of iron compd. in fluorobenzene-d5 to 1 atm of CO at 20°C for 12 h; NMR monitoring;

DOI:10.1021/ja806655f

upstream raw materials:

sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate

Downstream raw materials:

[Fe(η⁵-Cp*)(dppe)(CO)]BAr^F4