(6R,7S)-1-hydroxy-6,7-bis<4-(tert-butyldimethylsiloxy)phenyl>-5-nonanone

Base Information

Chemical Name:(6R*,7S*)-1-hydroxy-6,7-bis<4-(tert-butyldimethylsiloxy)phenyl>-5-nonanone
CAS No.:107036-20-4
Molecular Formula:C₃₃H₅₄O₄Si₂
Molecular Weight:570.96
Hs Code.:

Synonyms:(6R*,7S*)-1-hydroxy-6,7-bis<4-(tert-butyldimethylsiloxy)phenyl>-5-nonanone

Suppliers and Price of (6R*,7S*)-1-hydroxy-6,7-bis<4-(tert-butyldimethylsiloxy)phenyl>-5-nonanone

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (6R*,7S*)-1-hydroxy-6,7-bis<4-(tert-butyldimethylsiloxy)phenyl>-5-nonanone

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Technology Process of (6R*,7S*)-1-hydroxy-6,7-bis<4-(tert-butyldimethylsiloxy)phenyl>-5-nonanone

There total 1 articles about (6R*,7S*)-1-hydroxy-6,7-bis<4-(tert-butyldimethylsiloxy)phenyl>-5-nonanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 107036-19-1
(6R*,7S*)-6,7-bis<4-(tert-butyldimethylsiloxy)phenyl>-1-nonen-5-one

: 107036-20-4
(6R*,7S*)-1-hydroxy-6,7-bis<4-(tert-butyldimethylsiloxy)phenyl>-5-nonanone

Guidance literature:: With 9-borabicyclo[3.3.1]nonane dimer; In tetrahydrofuran; at 60 ℃; for 0.666667h;
DOI:10.1021/jm00388a015

Reference yield: 95.0%

: 124-63-0
methanesulfonyl chloride

: 107036-20-4
(6R*,7S*)-1-hydroxy-6,7-bis<4-(tert-butyldimethylsiloxy)phenyl>-5-nonanone

: 107036-21-5
(6R*,7S*)-5-oxo-6,7-bis<4-(tert-butyldimethylsiloxy)phenyl>-1-nonanyl methanesulfonate

Guidance literature:: With triethylamine; In tetrahydrofuran; for 0.333333h; Ambient temperature;
DOI:10.1021/jm00388a015

Reference yield:

: 107036-20-4
(6R*,7S*)-1-hydroxy-6,7-bis<4-(tert-butyldimethylsiloxy)phenyl>-5-nonanone

: 107036-07-7
(6R*,7S*)-1-N-aziridinyl-6,7-bis(4-hydroxyphenyl)-5-nonanone

Guidance literature:: Multi-step reaction with 3 steps

1: 95 percent / Et₃N / tetrahydrofuran / 0.33 h / Ambient temperature

2: 60 percent / p-TsOH*H₂O / ethyl acetate / 0.33 h / 40 °C

3: 54 percent / Et₃N / acetonitrile / 20 h / Ambient temperature

With toluene-4-sulfonic acid; triethylamine; In tetrahydrofuran; ethyl acetate; acetonitrile;
DOI:10.1021/jm00388a015