Vinyltriethoxysilane

Base Information

• Chemical Name: Vinyltriethoxysilane
• CAS No.: 78-08-0
• Deprecated CAS: 1029220-79-8,1609238-16-5,1633690-46-6,1233485-50-1,1391982-34-5
• Molecular Formula: C8H18O3Si
• Molecular Weight: 190.315
• Hs Code.: 29310095
• European Community (EC) Number: 201-081-7
• UNII: 8V1TKX755V
• DSSTox Substance ID: DTXSID3044463
• Nikkaji Number: J44.149J
• Wikipedia: Vinyltriethoxysilane
• Wikidata: Q27271055
• ChEMBL ID: CHEMBL3188350
• Mol file: 78-08-0.mol

Synonyms:triethoxyvinylsilane;vinyltriethoxysilane;VTES

Chemical Property of Vinyltriethoxysilane

Chemical Property:

• Appearance/Colour: Colorless transparent liquid
• Vapor Pressure: 3.09mmHg at 25°C
• Melting Point: <0 °C
• Refractive Index: n20/D 1.398(lit.)
• Boiling Point: 160.5 °C at 760 mmHg
• Flash Point: 34.4 °C
• PSA: 27.69000
• Density: 0.904 g/cm³
• LogP: 1.76000
• Storage Temp.: Flammables area
• Sensitive.: Moisture Sensitive
• Solubility.: Miscible with organic solvents.
• Water Solubility.: decomposes
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 7
• Exact Mass: 190.10252097
• Heavy Atom Count: 12
• Complexity: 111

Purity/Quality:

98% ^*data from raw suppliers

Triethoxyvinylsilane ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 10-36/37
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Metals -> Metalloid Compounds (Silicon)
• Canonical SMILES: CCO[Si](C=C)(OCC)OCC
• Description: vinyltriethoxysilane, is a vinyl-functional silane that may be used to improve the bond between glass fiber or mineral fillers and resins that are reactive towards the vinyl group. It is also employed to functionalize resins via free radical mechanisms - copolymerization or grafting - and to modify surfaces. vinyltriethoxysilane is mainly applied in these aspects: In the preparation of moisture-curing polymers, e.g. polyethylene. Silane crosslinked polyethylene is widely used as cable isolation, and sheathing mainly in low voltage applications as well as for hot water/sanitary pipes and underfloor heating. As a co-monomer for the preparation of different polymers such as polyethylene or acrylics. Those polymers show an improved adhesion to inorganic surfaces and they can also be crosslinked with moisture. As an efficient adhesion promoter for various mineral-filled polymers, improving mechanical and electrical properties especially after exposure to moisture. Improving the compatibility of fillers with polymers, leading to a better dispersibility, reduced melt viscosity and easier processing of filled plastics. Pre-treating of glass, metals, or ceramic surfaces, improve the adhesion of coatings on these surfaces and corrosion resistance. As moisture scavenger, it reacts rapidly with water. This effect is used widely in sealants.
• Uses: Vinyltriethoxysilane is used as an adhesive for glass slides. It acts as a coupling agent on inorganic substances blended into polymers that function as adhesion promoters, crosslinkers, and surface modifiers. Further, it is used to prepare polymers.

Technology Process of Vinyltriethoxysilane

There total 30 articles about Vinyltriethoxysilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

ethanol (64-17-5) + trichlorovinylsilane (75-94-5) → Triethoxyvinylsilane (78-08-0)

Guidance literature:

In dichloromethane; at 50 - 80 ℃; for 3h;

Reference yield: 96.7%

Triethoxysilane (998-30-1) + acetylene (74-86-2,25067-58-7) → Triethoxyvinylsilane (78-08-0)

Guidance literature:

at 90 ℃; under 225.023 - 375.038 Torr; Temperature;

Reference yield: 95.0%

tetraethoxy orthosilicate (78-10-4) + trichlorovinylsilane (75-94-5) → Triethoxyvinylsilane (78-08-0) + vinyldi(ethoxy)chlorosilane (18187-22-9) + vinyl(ethoxy)dichlorosilane (56124-75-5)

Guidance literature:

at 20 - 22 ℃; for 150h;

upstream raw materials:

ethanol

trichlorovinylsilane

Triethoxysilane

acetylene

Downstream raw materials:

bis-(2-methoxy-ethoxy)-divinyl-silane

methylvinyldiethoxysilane

ethoxydimethylvinylsilane

(diethoxy)(phenyl)(vinyl)silane

Refernces

Synthesis and x-ray structural characterization of Ru(PPh₃)₃(CO)(C₂H₄) and RuH(o-C₆H₄C(O)CH₃) (PPh₃)₂L (L = PPh₃, CO, DMSO): Ruthenium complexes

10.1021/om010393q

The research focuses on the synthesis and characterization of ruthenium complexes, specifically Ru(PPh3)3(CO)(C2H4) (1) and RuH(o-C6H4C(O)CH3)(PPh3)2L (2, L = PPh3; 3, L = CO; 4, L = DMSO), which are relevant to the Murai reaction—a catalytic process involving the insertion of alkenes into the ortho C-H bond of aromatic ketones. The purpose of this study was to assess the activity of these complexes in catalyzing the Murai reaction. The researchers found that the tris(phosphine) cyclometalated complex RuH(o-C6H4C(O)CH3)(PPh3)3 (2) was the most active among the catalyst precursors tested for the reaction of 2′-methylacetophenone with CH2dCHSi(OEt)3. However, substitution of the PPh3 ligand in the equatorial coordination site by CO resulted in a complex with essentially zero catalytic activity, indicating that a weakly bound ligand is necessary for activity. The study concluded that while the prepared complexes have structural similarities to proposed intermediates in the Murai reaction, further investigations are needed to fully understand the catalytic pathway. The chemicals used in the process include various ruthenium complexes, acetophenone, 2′-methylacetophenone, triethoxyvinylsilane, and solvents such as toluene and tetrahydrofuran (THF).