(Z)-(R)-3-Benzyloxycarbonyl-2-methyl-4-triethylsilanyloxy-hex-2-enedioic acid 1-benzyl ester 6-((1R,2R)-1-isopropyl-2-methoxy-3-oxo-propyl) ester

Base Information

Chemical Name:(Z)-(R)-3-Benzyloxycarbonyl-2-methyl-4-triethylsilanyloxy-hex-2-enedioic acid 1-benzyl ester 6-((1R,2R)-1-isopropyl-2-methoxy-3-oxo-propyl) ester
CAS No.:185670-28-4
Molecular Formula:C₃₅H₄₈O₉Si
Molecular Weight:640.846
Hs Code.:

Synonyms:(Z)-(R)-3-Benzyloxycarbonyl-2-methyl-4-triethylsilanyloxy-hex-2-enedioic acid 1-benzyl ester 6-((1R,2R)-1-isopropyl-2-methoxy-3-oxo-propyl) ester

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Chemical Property of (Z)-(R)-3-Benzyloxycarbonyl-2-methyl-4-triethylsilanyloxy-hex-2-enedioic acid 1-benzyl ester 6-((1R,2R)-1-isopropyl-2-methoxy-3-oxo-propyl) ester

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Technology Process of (Z)-(R)-3-Benzyloxycarbonyl-2-methyl-4-triethylsilanyloxy-hex-2-enedioic acid 1-benzyl ester 6-((1R,2R)-1-isopropyl-2-methoxy-3-oxo-propyl) ester

There total 4 articles about (Z)-(R)-3-Benzyloxycarbonyl-2-methyl-4-triethylsilanyloxy-hex-2-enedioic acid 1-benzyl ester 6-((1R,2R)-1-isopropyl-2-methoxy-3-oxo-propyl) ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 185670-27-3
(Z)-(R)-3-Benzyloxycarbonyl-2-methyl-4-triethylsilanyloxy-hex-2-enedioic acid 1-benzyl ester 6-{(R)-1-[(R)-methoxy-(methoxy-methyl-carbamoyl)-methyl]-2-methyl-propyl} ester

: 185670-28-4
(Z)-(R)-3-Benzyloxycarbonyl-2-methyl-4-triethylsilanyloxy-hex-2-enedioic acid 1-benzyl ester 6-((1R,2R)-1-isopropyl-2-methoxy-3-oxo-propyl) ester

Guidance literature:: With diisobutylaluminium hydride; In tetrahydrofuran; at -78 ℃; for 4h;
DOI:10.1021/jo961633s

Reference yield:

: 994-30-9
triethylsilyl chloride

: 185670-28-4
(Z)-(R)-3-Benzyloxycarbonyl-2-methyl-4-triethylsilanyloxy-hex-2-enedioic acid 1-benzyl ester 6-((1R,2R)-1-isopropyl-2-methoxy-3-oxo-propyl) ester

Guidance literature:: Multi-step reaction with 2 steps

2: 84 percent / DIBAL / tetrahydrofuran / 4 h / -78 °C

With diisobutylaluminium hydride; In tetrahydrofuran;
DOI:10.1021/jo961633s

Reference yield:

: 37976-44-6
dibenzylacetylene dicarboxylate

: 185670-28-4
(Z)-(R)-3-Benzyloxycarbonyl-2-methyl-4-triethylsilanyloxy-hex-2-enedioic acid 1-benzyl ester 6-((1R,2R)-1-isopropyl-2-methoxy-3-oxo-propyl) ester

Guidance literature:: Multi-step reaction with 3 steps

3: 84 percent / DIBAL / tetrahydrofuran / 4 h / -78 °C

With diisobutylaluminium hydride; In tetrahydrofuran;
DOI:10.1021/jo961633s