(2,3,7,8,12,13,17,18-octamethyl-5,10,15,20-tetraphenylporphinato)iron(III) chloride

Base Information

• Chemical Name: (2,3,7,8,12,13,17,18-octamethyl-5,10,15,20-tetraphenylporphinato)iron(III) chloride
• CAS No.: 186910-32-7
• Molecular Formula: C₅₂H₄₄ClFeN₄
• Molecular Weight: 816.248
• Mol file: 186910-32-7.mol

Synonyms:(2,3,7,8,12,13,17,18-octamethyl-5,10,15,20-tetraphenylporphinato)iron(III) chloride

Chemical Property of (2,3,7,8,12,13,17,18-octamethyl-5,10,15,20-tetraphenylporphinato)iron(III) chloride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of (2,3,7,8,12,13,17,18-octamethyl-5,10,15,20-tetraphenylporphinato)iron(III) chloride

There total 1 articles about (2,3,7,8,12,13,17,18-octamethyl-5,10,15,20-tetraphenylporphinato)iron(III) chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

2,3,7,8,12,13,17,18-octamethyl-5,10,15,20-tetraphenylporphyrine + iron(II) chloride → (2,3,7,8,12,13,17,18-octamethyl-5,10,15,20-tetraphenylporphinato)iron(III) chloride (186910-32-7)

Guidance literature:

With DMF; In N,N-dimethyl-formamide; recrystn. (CH2Cl2/ether);

DOI:10.1021/ja036398r

Reference yield: 67.0%

tetrahydrofuran (109-99-9,24979-97-3,77392-70-2) + (2,3,7,8,12,13,17,18-octamethyl-5,10,15,20-tetraphenylporphinato)iron(III) chloride (186910-32-7) + silver perchlorate → [Fe(5,10,15,20-tetraphenyl-2,3,7,8,12,13,17,18-octamethylporphyrin)(THF)2]ClO4 (353749-74-3)

Guidance literature:

In tetrahydrofuran; byproducts: AgCl; THF soln. of AgClO4 was added to THF soln. of Fe-complex, stirred for 1 min at room temp.; evapd., CH2Cl2 was added, filtered, evapd., THF was added, heptane was added, allowed to stand overnight, filtered, washed with hexane, dried invacuo for 10 min at 25°C;

DOI:10.1021/ic001412b

Reference yield:

2-methylimidazole (693-98-1) + (2,3,7,8,12,13,17,18-octamethyl-5,10,15,20-tetraphenylporphinato)iron(III) chloride (186910-32-7) + chloroform-d1 (865-49-6) → [Fe(octamethyltetraphenylporphyrinato)(2-methylimidazole)2]Cl * 2(chloroform-d)

Guidance literature:

In dichloromethane; placing of ligand in a soln. of Fe complex; crystals grown by liq. diffusion method using CDCl3 and cyclohexane;

DOI:10.1021/ja036398r

Downstream raw materials:

[Fe(5,10,15,20-tetraphenyl-2,3,7,8,12,13,17,18-octamethylporphyrin)(THF)2]ClO₄

paral-[Fe(octamethyltetraphenylporphyrinato)(1-methylimidazole)2]Cl * methylene chloride-d2

(2,3,7,8,12,13,17,18-octamethyl-5,10,15,20-tetraphenylporphyrin)iron(III) perchlorate

iron(III) octamethyltetraphenylporphyrin bis(4-cyanopyridine) perchlorate