trans,trans-(C₆F₅)(Ph₂P(CH₂)8CH=CH₂)2Pt(C₂)4Pt(Ph₂P(CH₂)8CHCH₂)2(C₆F₅)

Base Information

Chemical Name:trans,trans-(C₆F₅)(Ph₂P(CH₂)8CH=CH₂)2Pt(C₂)4Pt(Ph₂P(CH₂)8CHCH₂)2(C₆F₅)
CAS No.:945679-57-2
Molecular Formula:C₁₀₈H₁₁₆F₁₀P₄Pt₂
Molecular Weight:2118.15
Hs Code.:

trans,trans-(C<sub>6</sub>F<sub>5</sub>)(Ph<sub>2</sub>P(CH<sub>2</sub>)8CH=CH<sub>2</sub>)2Pt(C<sub>2</sub>)4Pt(Ph<sub>2</sub>P(CH<sub>2</sub>)8CHCH<sub>2</sub>)2(C<sub>6</sub>F<sub>5</sub>)

Synonyms:trans,trans-(C₆F₅)(Ph₂P(CH₂)8CH=CH₂)2Pt(C₂)4Pt(Ph₂P(CH₂)8CHCH₂)2(C₆F₅)

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Chemical Property of trans,trans-(C₆F₅)(Ph₂P(CH₂)8CH=CH₂)2Pt(C₂)4Pt(Ph₂P(CH₂)8CHCH₂)2(C₆F₅)

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Technology Process of trans,trans-(C₆F₅)(Ph₂P(CH₂)8CH=CH₂)2Pt(C₂)4Pt(Ph₂P(CH₂)8CHCH₂)2(C₆F₅)

There total 2 articles about trans,trans-(C₆F₅)(Ph₂P(CH₂)8CH=CH₂)2Pt(C₂)4Pt(Ph₂P(CH₂)8CHCH₂)2(C₆F₅) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

: 945679-65-2
trans-(C₆F₅)(Ph₂P(CH₂)8CH=CH₂)2Pt(C₂)2H

: 945679-57-2
trans,trans-(C₆F₅)(Ph₂P(CH₂)8CH=CH₂)2Pt(C₂)4Pt(Ph₂P(CH₂)8CHCH₂)2(C₆F₅)

Guidance literature:: With catalyst: CuI/N,N,N',N'-tetramethylethylenediamine; O₂; In acetone; O2, acetone, catalyst: CuCl/TMEDA; as oil;
DOI:10.1021/ja071612n

Reference yield: 73.0%

: 1777-03-3
2-triethylsilylacetylene

: 945679-65-2
trans-(C₆F₅)(Ph₂P(CH₂)8CH=CH₂)2Pt(C₂)2H

: 945679-60-7
trans-(C₆F₅)(Ph₂P(CH₂)8CH=CH₂)2Pt(C₂)3SiEt₃

: 945679-57-2
trans,trans-(C₆F₅)(Ph₂P(CH₂)8CH=CH₂)2Pt(C₂)4Pt(Ph₂P(CH₂)8CHCH₂)2(C₆F₅)

Guidance literature:: With catalyst:CuCl/N,N,N',N'-tetramethylethylenediamine; O₂; In acetone; O2 was bubbled through a soln. of complex and silane-compound in acetonewith stirring, the soln. was heated to 65°C, a soln. of CuCl/TME DA in acetone, stirred for 0.5 h, was added in portions over 2 h, 0.5 h; the solvent was rotary evapd., extd. with hexanes, then toluene, passed through an alumina column (toluene), rotary evapd., chromd. on silica gel column (90:10 v/v hexanes/CH2Cl2), the solvent was removed by oil pumping vac.; as oil; elem. anal.;
DOI:10.1021/ja071612n

Reference yield: 15.0%

: 945679-57-2
trans,trans-(C₆F₅)(Ph₂P(CH₂)8CH=CH₂)2Pt(C₂)4Pt(Ph₂P(CH₂)8CHCH₂)2(C₆F₅)

: 1333-74-0
hydrogen

: 945679-59-4,945679-71-0
trans,trans-(C₆F₅)(Ph₂P)2(CH₂)18Pt(C₂)4Pt(CH₂)18(Ph₂P)2(C₆F₅)

: trans,trans-(C₆F₅)(Ph₂P-(CH₂)18PPh₂)Pt-(C₂)4Pt-(Ph₂P(CH₂)18Ph₂P-)(C₆F₅)

Guidance literature:: With catalyst: Pd/C; Grubbs catalyst first generation; In ethanol; 1,2-dichloro-ethane; 1. 5-7% Crubbs'catalyst, Pd-complex and CH2Cl2, reflux for 5 h, chromd. on alumina column (CH2Cl2), rotary evapd.; 2. the crude mixt., 10% Pd/C,ClCH2CH2Cl2, ethanol, 1 atm. of H2, stirred for 14 d; the solvent was rotary evapd., the CH2Cl2-extract was passed through an alumina column (CH2Cl2), the solvent was removed by oil pump vac., chromy. on silica gel column (80:20 v/v hexanes/CH2Cl2);
DOI:10.1021/ja071612n