ethyl (2Z)-3-oxo-3-phenyl-2-(2-phenylhydrazinylidene)propanoate

Base Information

• Chemical Name: ethyl (2Z)-3-oxo-3-phenyl-2-(2-phenylhydrazinylidene)propanoate
• CAS No.: 60083-29-6
• Molecular Formula: C₁₇H₁₆N₂O₃
• Molecular Weight: 296.326
• Mol file: 60083-29-6.mol

Synonyms:ethyl (2Z)-3-oxo-3-phenyl-2-(2-phenylhydrazinylidene)propanoate

Chemical Property of ethyl (2Z)-3-oxo-3-phenyl-2-(2-phenylhydrazinylidene)propanoate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of ethyl (2Z)-3-oxo-3-phenyl-2-(2-phenylhydrazinylidene)propanoate

There total 3 articles about ethyl (2Z)-3-oxo-3-phenyl-2-(2-phenylhydrazinylidene)propanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

benzenediazonium tetrafluoroborate (369-57-3) + ethyl 3-oxo-3-phenylpropionate (94-02-0) → ethyl (2Z)-3-oxo-3-phenyl-2-(2-phenylhydrazinylidene)propanoate (60083-29-6)

Guidance literature:

With potassium carbonate; In dimethyl sulfoxide; at 90 ℃; for 2h;

DOI:10.1021/acs.joc.7b03149

Reference yield: 65.0%

benzene diazonium chloride (100-34-5) + ethyl 3-oxo-3-phenylpropionate (94-02-0) → ethyl (2Z)-3-oxo-3-phenyl-2-(2-phenylhydrazinylidene)propanoate (60083-29-6)

Guidance literature:

With sodium acetate; In ethanol; for 1h;

Reference yield: 60.0%

ethyl 3-oxo-3-phenylpropionate (94-02-0) + aniline (62-53-3) → ethyl (2Z)-3-oxo-3-phenyl-2-(2-phenylhydrazinylidene)propanoate (60083-29-6)

Guidance literature:

aniline; With hydrogenchloride; sodium nitrite; In water; at 0 - 5 ℃; for 0.166667h;

ethyl 3-oxo-3-phenylpropionate; With sodium acetate; In ethanol; water; at 5 - 20 ℃; for 2h; pH=5;

DOI:10.3390/molecules21020241

upstream raw materials:

benzene diazonium chloride

ethyl 3-oxo-3-phenylpropionate

aniline

benzenediazonium tetrafluoroborate

Downstream raw materials:

ethyl α-phenylhydrazonobenzoyl acetate

3-phenyl-4-phenylhydrazono-2-pyrazolin-5-one

ethyl 5-cyano-6-oxo-1,4-diphenyl-1,6-dihydropyridazine-3-carboxylate

5-Cyano-6-imino-1,4-diphenyl-1,6-dihydro-pyridazine-3-carboxylic acid ethyl ester