{(molybdenum)2(carbonyl)4(η-cyclopentadienyl)2(μ-(2,4,6-(t-Bu)3C6H2)phosphinidene)}

Base Information

Chemical Name:{(molybdenum)2(carbonyl)4(η-cyclopentadienyl)2(μ-(2,4,6-(t-Bu)3C6H2)phosphinidene)}
CAS No.:111464-90-5
Molecular Formula:C₃₂H₃₉Mo₂O₄P
Molecular Weight:710.513
Hs Code.:

Synonyms:{(molybdenum)2(carbonyl)4(η-cyclopentadienyl)2(μ-(2,4,6-(t-Bu)3C6H2)phosphinidene)}

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Chemical Property of {(molybdenum)2(carbonyl)4(η-cyclopentadienyl)2(μ-(2,4,6-(t-Bu)3C6H2)phosphinidene)}

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Technology Process of {(molybdenum)2(carbonyl)4(η-cyclopentadienyl)2(μ-(2,4,6-(t-Bu)3C6H2)phosphinidene)}

There total 7 articles about {(molybdenum)2(carbonyl)4(η-cyclopentadienyl)2(μ-(2,4,6-(t-Bu)3C6H2)phosphinidene)} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 480437-31-8
[Mo2(μ-H)(η5-cyclopentadienyl)2(PH(2,4,6-tBu3C6H2))(CO)4]

: 111464-90-5
{(molybdenum)2(carbonyl)4(η-cyclopentadienyl)2(μ-(2,4,6-(t-Bu)3C6H2)phosphinidene)}

Guidance literature:: With HBF₄*O(C₂H₅)2; H₂O; In not given;
DOI:10.1021/ja021072o

Reference yield: 45.0%

: [Mo₂Cp₂(μ-κ¹:κ¹,η⁶-P(2,4,6-C₆H₂^tBu₃))(CO)₂]

: 201230-82-2
carbon monoxide

: 111464-90-5
{(molybdenum)2(carbonyl)4(η-cyclopentadienyl)2(μ-(2,4,6-(t-Bu)3C6H2)phosphinidene)}

: [Mo2Cp2(μ-κ(1):κ(1),η(4)-2,4,6-PC6H2(t-Bu)3)(CO)3]

Guidance literature:: In toluene; (N2); std. Schlenk technique; soln. of Mo complex in toluene was cooled at 77 K; evacuated; refilled with CO; warmed to room temp.; stirred for 72 h; solvent removed (vac.); dissolved in CH2Cl2; chromd. (alumina, 288 K, CH2Cl2/petroleum ether, 1/6, than 1/3); solvent removed;
DOI:10.1021/om0605229

Reference yield: 22.0%

: potassium{molybdenum(carbonyl)3(η-cyclopentadienyl)}

: 79074-00-3
2,4,6-tri-t-butylphenylphosphonous dichloride

: 110655-35-1
((CH₃)3C)3C₆H₂P(H)P(Cl)C₆H₂(C(CH₃)3)3

: 111464-90-5
{(molybdenum)2(carbonyl)4(η-cyclopentadienyl)2(μ-(2,4,6-(t-Bu)3C6H2)phosphinidene)}

Guidance literature:: In tetrahydrofuran; byproducts: (C4H9)3C6H2PPC6H2(C4H9)3, (C4H9)3C6H2PH2, (C4H9)3C6H2P(H)P(H)C6H2(C4H9)3; treatment of soln. of (C4H9)3C6H2PCl2 in THF with 2 equivalents of potassium salt at -78°C; warming slowly to 25°C; detn. by (31)P-NMR; chromatography on silica gel with n-hexane with isolation of Mo dimer;
DOI:10.1016/S0277-5387(00)84575-1