(2E)-<2-<(2'R,5'R)-5'-<(tert-butyldimethylsilyl)oxy>-2'-methylcyclohexylidene>ethyl>diphenylphosphine oxide

Base Information

Chemical Name:(2E)-<2-<(2'R,5'R)-5'-<(tert-butyldimethylsilyl)oxy>-2'-methylcyclohexylidene>ethyl>diphenylphosphine oxide
CAS No.:141277-80-7
Molecular Formula:C₂₇H₃₉O₂PSi
Molecular Weight:454.665
Hs Code.:

Synonyms:(2E)-<2-<(2'R,5'R)-5'-<(tert-butyldimethylsilyl)oxy>-2'-methylcyclohexylidene>ethyl>diphenylphosphine oxide

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Chemical Property of (2E)-<2-<(2'R,5'R)-5'-<(tert-butyldimethylsilyl)oxy>-2'-methylcyclohexylidene>ethyl>diphenylphosphine oxide

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Technology Process of (2E)-<2-<(2'R,5'R)-5'-<(tert-butyldimethylsilyl)oxy>-2'-methylcyclohexylidene>ethyl>diphenylphosphine oxide

There total 12 articles about (2E)-<2-<(2'R,5'R)-5'-<(tert-butyldimethylsilyl)oxy>-2'-methylcyclohexylidene>ethyl>diphenylphosphine oxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 141277-84-1
(2E)-ethyl <(2'R,5'R)-5'-<(tert-butyldimethylsilyl)oxy>-2'-methylcyclohexylidene>ethanoate

: 141277-80-7
(2E)-<2-<(2'R,5'R)-5'-<(tert-butyldimethylsilyl)oxy>-2'-methylcyclohexylidene>ethyl>diphenylphosphine oxide

Guidance literature:: Multi-step reaction with 2 steps

1: diisobutylaluminium hydride / toluene / 1 h / -78 °C

With diisobutylaluminium hydride; In toluene;
DOI:10.1021/jo00045a038

Reference yield:

: 18162-48-6
tert-butyldimethylsilyl chloride

: 141277-80-7
(2E)-<2-<(2'R,5'R)-5'-<(tert-butyldimethylsilyl)oxy>-2'-methylcyclohexylidene>ethyl>diphenylphosphine oxide

Guidance literature:: Multi-step reaction with 4 steps

1: imidazole / dimethylformamide / 24 h

2: bis<2,2,2-trifluoro-1-phenyl-1-(trifluoromethyl)ethoxy>diphenylsulfurane / CCl₄ / 70 h / Ambient temperature

3: diisobutylaluminium hydride / toluene / 1 h / -78 °C

With 1H-imidazole; Martins sulfurane; diisobutylaluminium hydride; In tetrachloromethane; N,N-dimethyl-formamide; toluene;
DOI:10.1021/jo00045a038

Reference yield:

: 142980-89-0
ethyl <(2'R,5'R)-1',5-'dihydroxy-2'-methylcyclohexyl>ethanoate

: 141277-80-7
(2E)-<2-<(2'R,5'R)-5'-<(tert-butyldimethylsilyl)oxy>-2'-methylcyclohexylidene>ethyl>diphenylphosphine oxide

Guidance literature:: Multi-step reaction with 4 steps

1: imidazole / dimethylformamide / 24 h

2: bis<2,2,2-trifluoro-1-phenyl-1-(trifluoromethyl)ethoxy>diphenylsulfurane / CCl₄ / 70 h / Ambient temperature

3: diisobutylaluminium hydride / toluene / 1 h / -78 °C

With 1H-imidazole; Martins sulfurane; diisobutylaluminium hydride; In tetrachloromethane; N,N-dimethyl-formamide; toluene;
DOI:10.1021/jo00045a038