N-(triphenylphosphinegold)pivaloylamide

Base Information

Chemical Name:N-(triphenylphosphinegold)pivaloylamide
CAS No.:117199-32-3
Molecular Formula:C₂₃H₂₅AuNOP
Molecular Weight:559.398
Hs Code.:

Synonyms:N-(triphenylphosphinegold)pivaloylamide

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Chemical Property of N-(triphenylphosphinegold)pivaloylamide

Chemical Property:

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Technology Process of N-(triphenylphosphinegold)pivaloylamide

There total 1 articles about N-(triphenylphosphinegold)pivaloylamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 59.0%

: 53317-87-6
tris[triphenylphosphinegold(I)]oxonium tetrafluoroborate

: 754-10-9
2,2-dimethylpropionamide

: 117199-32-3
N-(triphenylphosphinegold)pivaloylamide

Guidance literature:: With K₂CO₃; In tetrahydrofuran; ethanol; water; 0.45 g of the amide dissolved in THF; water, ethanol, and 0.2 g K2CO3 added to the soln.; after 5 min, 2 g of the oxonium salt are dissolved in the soln. (20°C); soln. dried (K2CO3), solvent removed; residue dissolved in benzene, Au complex repptd. addn. of ether/petroleum ether (4:1); ppt. filtered off and dried under vac. over wax and P2O5 (36°C, 4 h); elem. anal.;

Reference yield: 35.0%

: 117199-32-3
N-(triphenylphosphinegold)pivaloylamide

: 97-77-8
disulfiram

: 754-10-9
2,2-dimethylpropionamide

: gold diethyldithiocarbamate

Guidance literature:: In ethanol; to a soln. of 0.11 g of the gold complex in EtOH is added a soln. of 0.06 g (Et2NC(S)S)2 in EtOH (20°C); the mixt. is stirred for 15 min; pptd. gold diethylthiocarbamate filtered off and washed with ether; mother liquor evapd. to dryness under vac., residue washed with benzene and recrystd. from alc.;

Reference yield: 21.0%

: 117199-32-3
N-(triphenylphosphinegold)pivaloylamide

: 7726-95-6
bromine

: 79384-10-4,14243-65-3
bromo(triphenylphosphine)gold(I)

: 24169-93-5,861015-35-2
triphenylphosphinegold(III) tribromide

: 754-10-9
2,2-dimethylpropionamide

: 7440-57-5,457905-15-6
gold

: 791-28-6
Triphenylphosphine oxide

Guidance literature:: In tetrachloromethane; dichloromethane; to a soln. of the gold complex in CH2Cl2 at -10°C is added a soln. of Br2 in CCl4; the mixt. is stirred for 20 min at the same temp.; the pptd. Au is sepd. off; petroleum ether precipitates a product mixt.; TLC indicates Ph3PO, Ph3PAuBr (content detd. from UV spectrum), and Ph3PAuBr3; pivaloylamide identified from IR spectrum;