(3aR,7R)-3a,7-Dimethyl-7-phenylsulfanylmethyl-4,5,6,7-tetrahydro-3aH-indene

Base Information

Chemical Name:(3aR,7R)-3a,7-Dimethyl-7-phenylsulfanylmethyl-4,5,6,7-tetrahydro-3aH-indene
CAS No.:213689-69-1
Molecular Formula:C₁₈H₂₂S
Molecular Weight:270.439
Hs Code.:

Synonyms:(3aR,7R)-3a,7-Dimethyl-7-phenylsulfanylmethyl-4,5,6,7-tetrahydro-3aH-indene

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Chemical Property of (3aR,7R)-3a,7-Dimethyl-7-phenylsulfanylmethyl-4,5,6,7-tetrahydro-3aH-indene

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Technology Process of (3aR,7R)-3a,7-Dimethyl-7-phenylsulfanylmethyl-4,5,6,7-tetrahydro-3aH-indene

There total 5 articles about (3aR,7R)-3a,7-Dimethyl-7-phenylsulfanylmethyl-4,5,6,7-tetrahydro-3aH-indene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 194931-07-2
Toluene-4-sulfonic acid (1S,4R,7aS)-4,7a-dimethyl-4-phenylsulfanylmethyl-2,4,5,6,7,7a-hexahydro-1H-inden-1-yl ester

: 213689-69-1
(3aR,7R)-3a,7-Dimethyl-7-phenylsulfanylmethyl-4,5,6,7-tetrahydro-3aH-indene

Guidance literature:: With potassium tert-butylate; In tetrahydrofuran; at 65 ℃; for 3.5h;
DOI:10.1002/(SICI)1521-3765(19980807)4:8<1480::AID-CHEM1480>3.0.CO;2-6

Reference yield:

: 51849-22-0
iodomethyl phenyl sulfide

: 213689-69-1
(3aR,7R)-3a,7-Dimethyl-7-phenylsulfanylmethyl-4,5,6,7-tetrahydro-3aH-indene

Guidance literature:: Multi-step reaction with 5 steps

1: KOBu-t / tetrahydrofuran / 1.) 0 deg C, 45 min, 2.) -78 deg C

2: 100 percent / HCl, H₂O / ethanol / 2 h / 25 °C

3: 87 percent / N₂H₄, H₂O, KOH / bis-(2-hydroxy-ethyl) ether / 1.) 100 deg C, 1 h, 2.) 200 deg C, 4 h

4: 99 percent / DMAP / CH₂Cl₂ / 16 h / 25 °C

5: 82 percent / KOBu-t / tetrahydrofuran / 3.5 h / 65 °C

With hydrogenchloride; dmap; potassium hydroxide; potassium tert-butylate; water; hydrazine; In tetrahydrofuran; ethanol; dichloromethane; diethylene glycol;
DOI:10.1002/(SICI)1521-3765(19980807)4:8<1480::AID-CHEM1480>3.0.CO;2-6

Reference yield:

: 194931-06-1
(1S,4R,7aS)-4,7a-Dimethyl-4-phenylsulfanylmethyl-2,4,5,6,7,7a-hexahydro-1H-inden-1-ol

: 213689-69-1
(3aR,7R)-3a,7-Dimethyl-7-phenylsulfanylmethyl-4,5,6,7-tetrahydro-3aH-indene

Guidance literature:: Multi-step reaction with 2 steps

1: 99 percent / DMAP / CH₂Cl₂ / 16 h / 25 °C

2: 82 percent / KOBu-t / tetrahydrofuran / 3.5 h / 65 °C

With dmap; potassium tert-butylate; In tetrahydrofuran; dichloromethane;
DOI:10.1002/(SICI)1521-3765(19980807)4:8<1480::AID-CHEM1480>3.0.CO;2-6