HacacSCH₂Ph

Base Information

• Chemical Name: HacacSCH₂Ph
• CAS No.: 1032739-12-0
• Molecular Formula: C₁₂H₁₄O₂S
• Molecular Weight: 222.308
• Mol file: 1032739-12-0.mol

Synonyms:HacacSCH₂Ph

Chemical Property of HacacSCH₂Ph

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of HacacSCH₂Ph

There total 1 articles about HacacSCH₂Ph which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

phenylmethanethiol (100-53-8) + acetylacetone (123-54-6,81235-32-7) → HacacSCH2Ph (1032739-12-0)

Guidance literature:

With sodium hydroxide; carbon tetrabromide; In dichloromethane; at 20 ℃; for 2h;

DOI:10.1021/ol800765s

Reference yield: 75.0%

HacacSCH2Ph (1032739-12-0) → F2BCH3COCOCCH3SCH2C6H5 (1186339-60-5)

Guidance literature:

With boric acid tributyl ester; boron trifluoride diethyl etherate; In diethyl ether; for 3h; Heating;

DOI:10.1134/S1070363208080094

Reference yield: 75.0%

boric acid tributyl ester (688-74-4) + HacacSCH2Ph (1032739-12-0) + boron trifluoride diethyl etherate (109-63-7) → F2BCH3COCOCCH3SCH2C6H5 (1186339-60-5)

Guidance literature:

In diethyl ether; mixture of diketone, BF3*Et2O and (BuO)3B in Et2O was stirred for 3 h; left overnight at 0°C, crystals were washed with Et2O at -20°C, dried in air, recrystd. from hexane, elem. anal.;

DOI:10.1134/S1070363208080094

upstream raw materials:

phenylmethanethiol

acetylacetone

Downstream raw materials:

F₂BCH₃COCOCCH₃SCH₂C₆H₅

Refernces

• 1、 -. "Method for synthesizing thioether compounds". Paragraph 0091-0093; 0134. . Retrieved 2018/09/11.