Di-tert-butyl tetrasulphide

Base Information

• Chemical Name: Di-tert-butyl tetrasulphide
• CAS No.: 5943-35-1
• Molecular Formula: C8H18 S4
• Molecular Weight: 242.495
• European Community (EC) Number: 227-704-2
• DSSTox Substance ID: DTXSID00871151
• Nikkaji Number: J81.121A
• Mol file: 5943-35-1.mol

Synonyms:5943-35-1;Di-tert-butyl tetrasulphide;di-tert-butyltetrasulfane;Di-tert-butyl pertetrasulfide;Di-tert.- Butyl-Tetrasulfid;SCHEMBL628225;DTXSID00871151;EINECS 227-704-2;2-tert-Butyldisulfanyldisulfanyl-2-methylpropane

Chemical Property of Di-tert-butyl tetrasulphide

Chemical Property:

• Vapor Pressure: 2E-10mmHg at 25°C
• Melting Point: 1.2°C
• Refractive Index: 1.5660 (estimate)
• Boiling Point: 507.6°C at 760 mmHg
• Flash Point: 260.8°C
• PSA: 101.20000
• Density: 1.163g/cm³
• LogP: 5.26120
• XLogP3: 3.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 5
• Exact Mass: 242.02913527
• Heavy Atom Count: 12
• Complexity: 104

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)(C)SSSSC(C)(C)C

Technology Process of Di-tert-butyl tetrasulphide

There total 23 articles about Di-tert-butyl tetrasulphide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

2-methylpropan-2-thiol (75-66-1) → bis(2-methyl-2-propyl)tetrasulfide (5943-35-1)

Guidance literature:

With disulfur dichloride;

DOI:10.1021/jacs.0c03626

Reference yield: 96.0%

di-tert-butyl disulfide (110-06-5) + acetonitrile (75-05-8,26809-02-9) → N-tert-butylacetamide (762-84-5) + bis(2-methyl-2-propyl)tetrasulfide (5943-35-1)

Guidance literature:

With water; lithium perchlorate; other nitriles; electrochemical oxidation;

DOI:10.1039/c39930000715

Reference yield: 96.0%

di-tert-butyl disulfide (110-06-5) + phenylacetonitrile (140-29-4) → bis(2-methyl-2-propyl)tetrasulfide (5943-35-1) + N-tert-butylphenylacetamide (6941-21-5)

Guidance literature:

With water; lithium perchlorate; electrochemical oxidation;

DOI:10.1039/c39930000715

upstream raw materials:

2-methylpropan-2-thiol

Di-tert-butyl dithiosulfite

di-tert-butyl disulfide

2,2,6,6-tetramethyl-3,5-dithiaheptane

Downstream raw materials:

tert-butyl o-methoxycarbonylphenyl disulfide