1,4-butanediol monoformate

Base Information

• Chemical Name: 1,4-butanediol monoformate
• CAS No.: 35435-67-7
• Molecular Formula: C₅H₁₀O₃
• Molecular Weight: 118.133
• Mol file: 35435-67-7.mol

Synonyms:1,4-butanediol monoformate

Chemical Property of 1,4-butanediol monoformate

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of 1,4-butanediol monoformate

There total 3 articles about 1,4-butanediol monoformate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 5.0%

Cyclopentanol (96-41-3) → 3,4,5,6-tetrahydro-2H-pyran-2-one (542-28-9,26354-94-9) + 5-iodovaleraldehyde (49540-03-6) + 1,4-butanediol monoformate (35435-67-7) + 2-tetrahydropyranyl ether of cyclopentanol (85382-33-8)

Guidance literature:

With iodine; mercury(II) oxide; In benzene; at 25 ℃; for 1.5h; Further byproducts given; Irradiation;

DOI:10.1016/S0040-4039(00)79598-0

Reference yield: 5.0%

Cyclopentanol (96-41-3) → 3,4,5,6-tetrahydro-2H-pyran-2-one (542-28-9,26354-94-9) + 5-iodovaleraldehyde (49540-03-6) + ω-Iodobutyl formate (85382-32-7) + 1,4-butanediol monoformate (35435-67-7) + 2-tetrahydropyranyl ether of cyclopentanol (85382-33-8)

Guidance literature:

With iodine; mercury(II) oxide; In benzene; at 25 ℃; for 1.5h; Product distribution; Mechanism; Irradiation; also with n-octanal; other reagent, other conditions;

DOI:10.1016/S0040-4039(00)79598-0

Reference yield:

Butane-1,4-diol (110-63-4) + carbon dioxide (124-38-9,18923-20-1) → 1,3-dioxepane (505-65-7) + formaldehyde-[bis-(4-hydroxy-butyl)-acetal] (101080-69-7) + 1,4-butanediol monoformate (35435-67-7)

Guidance literature:

With aluminium(III) triflate; [Ru(1,1,1-tris(diphenylphosphinomethyl)ethane)(trimethylenemethane)]; hydrogen; In 1,4-dioxane; at 80 ℃; for 18h; under 60006 Torr; Catalytic behavior; Autoclave; Schlenk technique;

DOI:10.1002/chem.201901660

upstream raw materials:

Cyclopentanol

Butane-1,4-diol

carbon dioxide

Refernces

• 1、 Courtneidge. "Alkoxyl radicals from alcohols I. The hypoiodite reaction of cyclopentanol: Evidence for sequential rather than competitive reaction pathways". . p. 3053 - 3056. Retrieved 2007/10/02.