(S)-6-Benzoylamino-4-[1-(2-hydroxy-phenyl)-meth-(E)-ylideneaminooxy]-6-oxo-hexanoic acid isopropyl ester

Base Information

Chemical Name:(S)-6-Benzoylamino-4-[1-(2-hydroxy-phenyl)-meth-(E)-ylideneaminooxy]-6-oxo-hexanoic acid isopropyl ester
CAS No.:809276-23-1
Molecular Formula:C₂₃H₂₆N₂O₆
Molecular Weight:426.469
Hs Code.:

Synonyms:(S)-6-Benzoylamino-4-[1-(2-hydroxy-phenyl)-meth-(E)-ylideneaminooxy]-6-oxo-hexanoic acid isopropyl ester

Suppliers and Price of (S)-6-Benzoylamino-4-[1-(2-hydroxy-phenyl)-meth-(E)-ylideneaminooxy]-6-oxo-hexanoic acid isopropyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (S)-6-Benzoylamino-4-[1-(2-hydroxy-phenyl)-meth-(E)-ylideneaminooxy]-6-oxo-hexanoic acid isopropyl ester

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (S)-6-Benzoylamino-4-[1-(2-hydroxy-phenyl)-meth-(E)-ylideneaminooxy]-6-oxo-hexanoic acid isopropyl ester

There total 2 articles about (S)-6-Benzoylamino-4-[1-(2-hydroxy-phenyl)-meth-(E)-ylideneaminooxy]-6-oxo-hexanoic acid isopropyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 21013-96-7
(E)-2-hydroxylbenzaldehyde oxime

: 809275-89-6
(E)-6-Benzoylamino-6-oxo-hex-4-enoic acid isopropyl ester

: 809276-23-1
(S)-6-Benzoylamino-4-[1-(2-hydroxy-phenyl)-meth-(E)-ylideneaminooxy]-6-oxo-hexanoic acid isopropyl ester

Guidance literature:: With [(R,R)-(N,N'-bis(3,5-di-tBu-salicylidene)-C₄H₈-diimine)Al]2O; In cyclohexane; at 23 ℃; for 48h;
DOI:10.1021/ja045563f

Reference yield:

: 247043-57-8
(2-benzoylamino-2-oxoethyl)phosphonic acid diethyl ester

: 809276-23-1
(S)-6-Benzoylamino-4-[1-(2-hydroxy-phenyl)-meth-(E)-ylideneaminooxy]-6-oxo-hexanoic acid isopropyl ester

Guidance literature:: Multi-step reaction with 2 steps

1.1: n-BuLi / tetrahydrofuran; hexane / 0.25 h / -78 °C

1.2: tetrahydrofuran; hexane / -78 - 0 °C

2.1: [(R,R)-(N,N'-bis(3,5-di-tBu-salicylidene)-C₄H₈-diimine)Al]2O / cyclohexane / 48 h / 23 °C

With n-butyllithium; [(R,R)-(N,N'-bis(3,5-di-tBu-salicylidene)-C₄H₈-diimine)Al]2O; In tetrahydrofuran; hexane; cyclohexane; 1.2: Horner-Wadsworth-Emmons olefination;
DOI:10.1021/ja045563f