5-(4-bis(9,9-dimethyl-9H-fluoren-2-yl)amino)-10,15-diphenyl-20-(4-cyanophenyl)porphyrin zinc(II)

Base Information

Chemical Name:5-(4-bis(9,9-dimethyl-9H-fluoren-2-yl)amino)-10,15-diphenyl-20-(4-cyanophenyl)porphyrin zinc(II)
CAS No.:1398574-29-2
Molecular Formula:C₆₉H₄₈N₆Zn
Molecular Weight:1026.57
Hs Code.:

Synonyms:5-(4-bis(9,9-dimethyl-9H-fluoren-2-yl)amino)-10,15-diphenyl-20-(4-cyanophenyl)porphyrin zinc(II)

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Chemical Property of 5-(4-bis(9,9-dimethyl-9H-fluoren-2-yl)amino)-10,15-diphenyl-20-(4-cyanophenyl)porphyrin zinc(II)

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Technology Process of 5-(4-bis(9,9-dimethyl-9H-fluoren-2-yl)amino)-10,15-diphenyl-20-(4-cyanophenyl)porphyrin zinc(II)

There total 5 articles about 5-(4-bis(9,9-dimethyl-9H-fluoren-2-yl)amino)-10,15-diphenyl-20-(4-cyanophenyl)porphyrin zinc(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

: 500717-23-7
N-(9,9-dimethyl-9H-fluoren- 2-yl)-9,9-dimethyl-9H-fluoren-2-amine

: 1398574-28-1
5,15-di(phenyl)-10-(bromo)-20-(4-benzonitrile)porphyrin zinc(II)

: 1398574-29-2
5-(4-bis(9,9-dimethyl-9H-fluoren-2-yl)amino)-10,15-diphenyl-20-(4-cyanophenyl)porphyrin zinc(II)

Guidance literature:: With palladium diacetate; sodium hydride; bis[2-(diphenylphosphino)phenyl] ether; In tetrahydrofuran; mineral oil; at 80 ℃; for 24h; Schlenk technique; Inert atmosphere;

Reference yield:

: 21211-65-4
di(pyrrol-2-yl)methane

: 1398574-29-2
5-(4-bis(9,9-dimethyl-9H-fluoren-2-yl)amino)-10,15-diphenyl-20-(4-cyanophenyl)porphyrin zinc(II)

Guidance literature:: Multi-step reaction with 4 steps

1.1: boron trifluoride diethyl etherate / chloroform / 2 h / 20 °C

1.2: 12 h

2.1: N-Bromosuccinimide / chloroform / 12 h / Reflux

3.1: zinc diacetate / tetrahydrofuran / 12 h / Reflux

4.1: palladium diacetate; bis[2-(diphenylphosphino)phenyl] ether; sodium hydride / tetrahydrofuran; mineral oil / 48 h / Reflux

With N-Bromosuccinimide; boron trifluoride diethyl etherate; zinc diacetate; palladium diacetate; sodium hydride; bis[2-(diphenylphosphino)phenyl] ether; In tetrahydrofuran; chloroform; mineral oil;
DOI:10.1039/c2cc31384g DOI:10.1039/c2cc31384g

Reference yield:

: 100-52-7
benzaldehyde

: 1398574-29-2
5-(4-bis(9,9-dimethyl-9H-fluoren-2-yl)amino)-10,15-diphenyl-20-(4-cyanophenyl)porphyrin zinc(II)

Guidance literature:: Multi-step reaction with 4 steps

1.1: boron trifluoride diethyl etherate / chloroform / 2 h / 20 °C

1.2: 12 h

2.1: N-Bromosuccinimide / chloroform / 12 h / Reflux

3.1: zinc diacetate / tetrahydrofuran / 12 h / Reflux

4.1: palladium diacetate; bis[2-(diphenylphosphino)phenyl] ether; sodium hydride / tetrahydrofuran; mineral oil / 48 h / Reflux

With N-Bromosuccinimide; boron trifluoride diethyl etherate; zinc diacetate; palladium diacetate; sodium hydride; bis[2-(diphenylphosphino)phenyl] ether; In tetrahydrofuran; chloroform; mineral oil;
DOI:10.1039/c2cc31384g DOI:10.1039/c2cc31384g