5-(4-bis(9,9-dimethyl-9H-fluoren-2-yl)amino)-10,15-diphenyl-20-(4-formylphenyl)porphyrin zinc(II)

Base Information

• Chemical Name: 5-(4-bis(9,9-dimethyl-9H-fluoren-2-yl)amino)-10,15-diphenyl-20-(4-formylphenyl)porphyrin zinc(II)
• CAS No.: 1398574-30-5
• Molecular Formula: C₆₉H₄₉N₅OZn
• Molecular Weight: 1029.57
• Mol file: 1398574-30-5.mol

Synonyms:5-(4-bis(9,9-dimethyl-9H-fluoren-2-yl)amino)-10,15-diphenyl-20-(4-formylphenyl)porphyrin zinc(II)

Chemical Property of 5-(4-bis(9,9-dimethyl-9H-fluoren-2-yl)amino)-10,15-diphenyl-20-(4-formylphenyl)porphyrin zinc(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 5-(4-bis(9,9-dimethyl-9H-fluoren-2-yl)amino)-10,15-diphenyl-20-(4-formylphenyl)porphyrin zinc(II)

There total 1 articles about 5-(4-bis(9,9-dimethyl-9H-fluoren-2-yl)amino)-10,15-diphenyl-20-(4-formylphenyl)porphyrin zinc(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

5-(4-bis(9,9-dimethyl-9H-fluoren-2-yl)amino)-10,15-diphenyl-20-(4-cyanophenyl)porphyrin zinc(II) (1398574-29-2) → 5-(4-bis(9,9-dimethyl-9H-fluoren-2-yl)amino)-10,15-diphenyl-20-(4-formylphenyl)porphyrin zinc(II) (1398574-30-5)

Guidance literature:

5-(4-bis(9,9-dimethyl-9H-fluoren-2-yl)amino)-10,15-diphenyl-20-(4-cyanophenyl)porphyrin zinc(II); With diisobutylaluminium hydride; In hexane; dichloromethane; at 0 - 20 ℃; for 4h; Inert atmosphere;

In hexane; dichloromethane;

DOI:10.1039/c2cc31384g DOI:10.1039/c2cc31384g

Reference yield: 80.0%

5-(4-bis(9,9-dimethyl-9H-fluoren-2-yl)amino)-10,15-diphenyl-20-(4-formylphenyl)porphyrin zinc(II) (1398574-30-5) + cyanoacetic acid (372-09-8) → 5-(4-bis(9,9-dimethyl-9H-fluoren-2-yl)amino)-10,15-diphenyl-20-(4-cyanoacrylphenyl)porphyrin zinc(II) (1398574-24-7)

Guidance literature:

With piperidine; In acetonitrile; for 24h; Reflux;

DOI:10.1039/c2cc31384g DOI:10.1039/c2cc31384g

Reference yield: 70.0%

5-(4-bis(9,9-dimethyl-9H-fluoren-2-yl)amino)-10,15-diphenyl-20-(4-formylphenyl)porphyrin zinc(II) (1398574-30-5) + 2-cyanoacrylic acid (15802-18-3) → 5-(4-bis(9,9-dimethyl-9H-fluoren-2-yl)amino)-10,15-diphenyl-20-(4-cyanoacrylphenyl)porphyrin zinc(II) (1398574-24-7)

Guidance literature:

With piperidine; In acetonitrile; at 100 ℃; for 24h;

upstream raw materials:

5-(4-bis(9,9-dimethyl-9H-fluoren-2-yl)amino)-10,15-diphenyl-20-(4-cyanophenyl)porphyrin zinc(II)

Downstream raw materials:

5-(4-bis(9,9-dimethyl-9H-fluoren-2-yl)amino)-10,15-diphenyl-20-(4-cyanoacrylphenyl)porphyrin zinc(II)