S-(4-methylphenyl) 3-acetamido-2,6-anhydro-4,5,7-tri-O-benzyl-3-deoxy-D-glycero-D-ido-hepto-pyranosonothioate

Base Information

• Chemical Name: S-(4-methylphenyl) 3-acetamido-2,6-anhydro-4,5,7-tri-O-benzyl-3-deoxy-D-glycero-D-ido-hepto-pyranosonothioate
• CAS No.: 768385-14-4
• Molecular Formula: C₃₇H₃₉NO₆S
• Molecular Weight: 625.786
• Mol file: 768385-14-4.mol

Synonyms:S-(4-methylphenyl) 3-acetamido-2,6-anhydro-4,5,7-tri-O-benzyl-3-deoxy-D-glycero-D-ido-hepto-pyranosonothioate

Chemical Property of S-(4-methylphenyl) 3-acetamido-2,6-anhydro-4,5,7-tri-O-benzyl-3-deoxy-D-glycero-D-ido-hepto-pyranosonothioate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of S-(4-methylphenyl) 3-acetamido-2,6-anhydro-4,5,7-tri-O-benzyl-3-deoxy-D-glycero-D-ido-hepto-pyranosonothioate

There total 1 articles about S-(4-methylphenyl) 3-acetamido-2,6-anhydro-4,5,7-tri-O-benzyl-3-deoxy-D-glycero-D-ido-hepto-pyranosonothioate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

para-thiocresol (106-45-6) + 3-acetamido-2,6-anhydro-4,5,7-tri-O-benzyl-3-deoxy-D-glycero-D-ido-heptonic acid (260551-08-4) → S-(4-methylphenyl) 3-acetamido-2,6-anhydro-4,5,7-tri-O-benzyl-3-deoxy-D-glycero-D-ido-hepto-pyranosonothioate (768385-14-4)

Guidance literature:

3-acetamido-2,6-anhydro-4,5,7-tri-O-benzyl-3-deoxy-D-glycero-D-ido-heptonic acid; With 1,1'-carbonyldiimidazole; In N,N-dimethyl-formamide; at 0 - 20 ℃; for 2.5h;

para-thiocresol; In N,N-dimethyl-formamide; at 20 ℃; for 1.5h;

DOI:10.1002/ejoc.200400197

Reference yield: 93.0%

S-(4-methylphenyl) 3-acetamido-2,6-anhydro-4,5,7-tri-O-benzyl-3-deoxy-D-glycero-D-ido-hepto-pyranosonothioate (768385-14-4) → 3-acetamido-2,6-anhydro-4,5,7-tri-O-benzyl-3-deoxy-1-hydroxy-D-glycero-D-ido-heptitol (260551-11-9)

Guidance literature:

With sodium tetrahydroborate; In ethanol; dichloromethane; at 0 - 20 ℃; for 3h;

DOI:10.1002/ejoc.200400197

upstream raw materials:

para-thiocresol

3-acetamido-2,6-anhydro-4,5,7-tri-O-benzyl-3-deoxy-D-glycero-D-ido-heptonic acid

Downstream raw materials:

3-acetamido-2,6-anhydro-4,5,7-tri-O-benzyl-3-deoxy-1-hydroxy-D-glycero-D-ido-heptitol