1-ethenyl-1H-tetrazol-5-amine

Base Information

• Chemical Name: 1-ethenyl-1H-tetrazol-5-amine
• CAS No.: 15284-33-0
• Molecular Formula: C3H5 N5
• Molecular Weight: 111.106
• Mol file: 15284-33-0.mol

Synonyms:1H-Tetrazole,5-amino-1-vinyl- (6CI,7CI,8CI); 5-Amino-1-vinyltetrazole; NSC 206241; NSC282093

Chemical Property of 1-ethenyl-1H-tetrazol-5-amine

Chemical Property:

• Vapor Pressure: 0.00294mmHg at 25°C
• Boiling Point: 284.7°C at 760 mmHg
• Flash Point: 126°C
• Density: 1.52g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1-ethenyl-1H-tetrazol-5-amine

There total 4 articles about 1-ethenyl-1H-tetrazol-5-amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

5-aminotetrazole (4418-61-5) + vinyl acetate (108-05-4,9003-20-7) → 1-vinyl-5-amino[1,2,3,4]tetrazole (15284-33-0)

Guidance literature:

boron trifluoride diethyl etherate; mercury(II) diacetate; In various solvent(s); at 50 - 55 ℃; for 2h;

Reference yield: 53.0%

5-aminotetrazole (4418-61-5) + ethylene dibromide (106-93-4) → 5-amino-2-(vinyl)-2H-tetrazole (15284-34-1) + 1-vinyl-5-amino[1,2,3,4]tetrazole (15284-33-0)

Guidance literature:

With triethylamine; In acetonitrile; regioselective reaction; Reflux;

DOI:10.1134/S1070428011120177

Reference yield:

1-(2-chloroethyl)-5-aminotetrazole (15284-31-8) → 1-vinyl-5-amino[1,2,3,4]tetrazole (15284-33-0)

Guidance literature:

With potassium hydroxide; hydroquinone;

DOI:10.1021/jo01092a602

upstream raw materials:

1-(2-chloroethyl)-5-aminotetrazole

5-aminotetrazole

vinyl acetate

ethylene dibromide

Downstream raw materials:

Cu(1-vinyl-5-aminotetrazole)2Cl₂

Pd(1-vinyl-5-aminotetrazole)2Cl₂

Ni(1-vinyl-5-aminotetrazole)2Cl₂

Refernces

• 1、 Youssef, Carlos,Backov, Renal,Treguer, Mona,Birot, Marc,Deleuze, Herve. "Preparation of remarkably tough polyHIPE materials via polymerization of oil-in-water HIPEs involving 1-vinyl-5-aminotetrazole". experimental part. p. 2942 - 2947. Retrieved 2011/03/18.