vinyl 4,6-di-O-benzyl-2,3-dideoxy-α-D-erythro-hex-2-enopyranoside

Base Information

Chemical Name:vinyl 4,6-di-O-benzyl-2,3-dideoxy-α-D-erythro-hex-2-enopyranoside
CAS No.:1581704-99-5
Molecular Formula:C₂₂H₂₄O₄
Molecular Weight:352.43
Hs Code.:

Synonyms:vinyl 4,6-di-O-benzyl-2,3-dideoxy-α-D-erythro-hex-2-enopyranoside

Suppliers and Price of vinyl 4,6-di-O-benzyl-2,3-dideoxy-α-D-erythro-hex-2-enopyranoside

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of vinyl 4,6-di-O-benzyl-2,3-dideoxy-α-D-erythro-hex-2-enopyranoside

Chemical Property:

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Technology Process of vinyl 4,6-di-O-benzyl-2,3-dideoxy-α-D-erythro-hex-2-enopyranoside

There total 5 articles about vinyl 4,6-di-O-benzyl-2,3-dideoxy-α-D-erythro-hex-2-enopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 2873-29-2
D-glucal triacetate

: 1581704-99-5
vinyl 4,6-di-O-benzyl-2,3-dideoxy-α-D-erythro-hex-2-enopyranoside

Guidance literature:: Multi-step reaction with 5 steps

1.1: boron trifluoride diethyl etherate / benzene / 0 - 25 °C / Inert atmosphere

2.1: methanol; potassium carbonate / 3 h / Inert atmosphere

3.1: sodium hydride / tetrahydrofuran / 1.33 h / 0 °C / Inert atmosphere

3.2: 25 °C / Inert atmosphere

4.1: sodium periodate; sodium hydrogencarbonate / methanol; water / 1 h / 25 °C / Inert atmosphere

5.1: diisopropylamine / benzene / 0.5 h / Inert atmosphere; Reflux

With methanol; sodium periodate; boron trifluoride diethyl etherate; sodium hydride; sodium hydrogencarbonate; potassium carbonate; diisopropylamine; In tetrahydrofuran; methanol; water; benzene; 1.1: |Ferrier Carbohydrate Rearrangement;
DOI:10.1002/ejoc.201301665

Reference yield:

: 89755-42-0
<2'-(Phenylselenenyl)-ethyl>-4,6-di-O-acetyl-2,3-dideoxy-α-D-erythro-hexenopyranoside

: 1581704-99-5
vinyl 4,6-di-O-benzyl-2,3-dideoxy-α-D-erythro-hex-2-enopyranoside

Guidance literature:: Multi-step reaction with 4 steps

1.1: methanol; potassium carbonate / 3 h / Inert atmosphere

2.1: sodium hydride / tetrahydrofuran / 1.33 h / 0 °C / Inert atmosphere

2.2: 25 °C / Inert atmosphere

3.1: sodium periodate; sodium hydrogencarbonate / methanol; water / 1 h / 25 °C / Inert atmosphere

4.1: diisopropylamine / benzene / 0.5 h / Inert atmosphere; Reflux

With methanol; sodium periodate; sodium hydride; sodium hydrogencarbonate; potassium carbonate; diisopropylamine; In tetrahydrofuran; methanol; water; benzene;
DOI:10.1002/ejoc.201301665

Reference yield:

: 1581704-97-3
2-phenylselenenylethyl 4,6-di-O-benzyl-2,3-dideoxy-α-D-erythrohex-2-enopyranoside

: 1581704-99-5
vinyl 4,6-di-O-benzyl-2,3-dideoxy-α-D-erythro-hex-2-enopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: sodium periodate; sodium hydrogencarbonate / methanol; water / 1 h / 25 °C / Inert atmosphere

2: diisopropylamine / benzene / 0.5 h / Inert atmosphere; Reflux

With sodium periodate; sodium hydrogencarbonate; diisopropylamine; In methanol; water; benzene;
DOI:10.1002/ejoc.201301665