Thioacetic acid S-(1-benzenesulfonyl-3-phenyl-propyl) ester

Base Information

• Chemical Name: Thioacetic acid S-(1-benzenesulfonyl-3-phenyl-propyl) ester
• CAS No.: 115120-16-6
• Molecular Formula: C₁₇H₁₈O₃S₂
• Molecular Weight: 334.46
• Mol file: 115120-16-6.mol

Synonyms:Thioacetic acid S-(1-benzenesulfonyl-3-phenyl-propyl) ester

Chemical Property of Thioacetic acid S-(1-benzenesulfonyl-3-phenyl-propyl) ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Thioacetic acid S-(1-benzenesulfonyl-3-phenyl-propyl) ester

There total 3 articles about Thioacetic acid S-(1-benzenesulfonyl-3-phenyl-propyl) ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

Thioacetic acid S-(3-phenyl-1-phenylsulfanyl-propyl) ester (115120-13-3) → Thioacetic acid S-(1-benzenesulfonyl-3-phenyl-propyl) ester (115120-16-6)

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 0 ℃; for 1h;

DOI:10.1021/ja00224a033

Reference yield:

phenyl 3-phenylpropyl sulfide (30134-12-4) → Thioacetic acid S-(1-benzenesulfonyl-3-phenyl-propyl) ester (115120-16-6)

Guidance literature:

Multi-step reaction with 3 steps

1: N-chlorosuccinimide / CCl₄

2: K₂CO₃ / acetonitrile / 2.5 h

3: 73 percent / MCPBA / CH₂Cl₂ / 1 h / 0 °C

With N-chloro-succinimide; potassium carbonate; 3-chloro-benzenecarboperoxoic acid; In tetrachloromethane; dichloromethane; acetonitrile;

DOI:10.1021/ja00224a033

Reference yield:

C15H15ClS (58749-31-8) → Thioacetic acid S-(1-benzenesulfonyl-3-phenyl-propyl) ester (115120-16-6)

Guidance literature:

Multi-step reaction with 2 steps

1: K₂CO₃ / acetonitrile / 2.5 h

2: 73 percent / MCPBA / CH₂Cl₂ / 1 h / 0 °C

With potassium carbonate; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; acetonitrile;

DOI:10.1021/ja00224a033

upstream raw materials:

Thioacetic acid S-(3-phenyl-1-phenylsulfanyl-propyl) ester

phenyl 3-phenylpropyl sulfide

C₁₅H₁₅ClS

Downstream raw materials:

(1R,3S,4S)-3-Phenethyl-2-thia-bicyclo[2.2.1]hept-5-ene

(1S,3S,4R)-3-Phenethyl-2-thia-bicyclo[2.2.1]hept-5-ene