methyl (4S)-2,3,6-tri-O-benzyl-4-deoxy-4-C-((3,4,6-tri-O-benzyl-1,2-dideoxy-D-arabino-hex-1-enyl)-2-propene)-α-D-glucopyranoside

Base Information

Chemical Name:methyl (4S)-2,3,6-tri-O-benzyl-4-deoxy-4-C-((3,4,6-tri-O-benzyl-1,2-dideoxy-D-arabino-hex-1-enyl)-2-propene)-α-D-glucopyranoside
CAS No.:365418-08-2
Molecular Formula:C₅₈H₆₄O₉
Molecular Weight:905.141
Hs Code.:

Synonyms:methyl (4S)-2,3,6-tri-O-benzyl-4-deoxy-4-C-((3,4,6-tri-O-benzyl-1,2-dideoxy-D-arabino-hex-1-enyl)-2-propene)-α-D-glucopyranoside

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Chemical Property of methyl (4S)-2,3,6-tri-O-benzyl-4-deoxy-4-C-((3,4,6-tri-O-benzyl-1,2-dideoxy-D-arabino-hex-1-enyl)-2-propene)-α-D-glucopyranoside

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Technology Process of methyl (4S)-2,3,6-tri-O-benzyl-4-deoxy-4-C-((3,4,6-tri-O-benzyl-1,2-dideoxy-D-arabino-hex-1-enyl)-2-propene)-α-D-glucopyranoside

There total 11 articles about methyl (4S)-2,3,6-tri-O-benzyl-4-deoxy-4-C-((3,4,6-tri-O-benzyl-1,2-dideoxy-D-arabino-hex-1-enyl)-2-propene)-α-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 51.0%

: 365418-07-1
methyl (4S)-2,3,6-tri-O-benzyl-4-deoxy-4-C-((3,4,6-tri-O-benzyl-1,2-dideoxy-D-arabino-hex-1-enyl)-(2-ethanoate))-α-D-glucopyranoside

: 74-95-3
1,1-dibromomethane

: 365418-08-2
methyl (4S)-2,3,6-tri-O-benzyl-4-deoxy-4-C-((3,4,6-tri-O-benzyl-1,2-dideoxy-D-arabino-hex-1-enyl)-2-propene)-α-D-glucopyranoside

Guidance literature:: With N,N,N,N,-tetramethylethylenediamine; titanium tetrachloride; zinc; lead(II) chloride; In tetrahydrofuran; dichloromethane; at 60 ℃; for 1h;
DOI:10.1021/ja010641+ DOI:10.1021/jo030039x

Reference yield:

: 365418-30-0
methyl (4S)-2,3,6-tri-O-benzyl-4-deoxy-4-(2-ethanal)-α-D-glucopyranoside

: 365418-08-2
methyl (4S)-2,3,6-tri-O-benzyl-4-deoxy-4-C-((3,4,6-tri-O-benzyl-1,2-dideoxy-D-arabino-hex-1-enyl)-2-propene)-α-D-glucopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1: 2-methyl-2-butene; NaH₂PO₄; NaClO₂ / 2-methyl-propan-2-ol; H₂O / 1 h / 20 °C

2: 82 percent / 4-DMAP; DCC / CH₂Cl₂ / 18 h / 20 °C

3: 51 percent / TiCl₄; Zn; TMEDA / PbCl₂ / CH₂Cl₂; tetrahydrofuran / 1 h / 60 °C

With dmap; sodium chlorite; sodium dihydrogenphosphate; 2-methyl-but-2-ene; N,N,N,N,-tetramethylethylenediamine; titanium tetrachloride; dicyclohexyl-carbodiimide; zinc; lead(II) chloride; In tetrahydrofuran; dichloromethane; water; tert-butyl alcohol;
DOI:10.1021/jo030039x

Reference yield:

: 102208-53-7
(3R,4R,5R)-5-hydroxy-3,4,6-tribenzyloxy-1-hexene

: 365418-08-2
methyl (4S)-2,3,6-tri-O-benzyl-4-deoxy-4-C-((3,4,6-tri-O-benzyl-1,2-dideoxy-D-arabino-hex-1-enyl)-2-propene)-α-D-glucopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 82 percent / 4-DMAP; DCC / CH₂Cl₂ / 18 h / 20 °C

2: 51 percent / TiCl₄; Zn; TMEDA / PbCl₂ / CH₂Cl₂; tetrahydrofuran / 1 h / 60 °C

With dmap; N,N,N,N,-tetramethylethylenediamine; titanium tetrachloride; dicyclohexyl-carbodiimide; zinc; lead(II) chloride; In tetrahydrofuran; dichloromethane;
DOI:10.1021/jo030039x