(1S,2R,5S)-5-methyl-2-(2-phenylprop-2-yl)cyclohexyl (E)-5-(3,3-dimethyloxiran-2-yl)-3-methylpent-2-enoate

Base Information

Chemical Name:(1S,2R,5S)-5-methyl-2-(2-phenylprop-2-yl)cyclohexyl (E)-5-(3,3-dimethyloxiran-2-yl)-3-methylpent-2-enoate
CAS No.:1335013-04-1
Molecular Formula:C₂₆H₃₈O₃
Molecular Weight:398.586
Hs Code.:

Synonyms:(1S,2R,5S)-5-methyl-2-(2-phenylprop-2-yl)cyclohexyl (E)-5-(3,3-dimethyloxiran-2-yl)-3-methylpent-2-enoate

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Chemical Property of (1S,2R,5S)-5-methyl-2-(2-phenylprop-2-yl)cyclohexyl (E)-5-(3,3-dimethyloxiran-2-yl)-3-methylpent-2-enoate

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Technology Process of (1S,2R,5S)-5-methyl-2-(2-phenylprop-2-yl)cyclohexyl (E)-5-(3,3-dimethyloxiran-2-yl)-3-methylpent-2-enoate

There total 3 articles about (1S,2R,5S)-5-methyl-2-(2-phenylprop-2-yl)cyclohexyl (E)-5-(3,3-dimethyloxiran-2-yl)-3-methylpent-2-enoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 1335013-09-6
(1S,5S)-5-methyl-2-(2-phenylprop-2-yl)cyclohexyl (E)-3,7-dimethylocta-2,6-dienoate

: 1335013-04-1
(1S,2R,5S)-5-methyl-2-(2-phenylprop-2-yl)cyclohexyl (E)-5-(3,3-dimethyloxiran-2-yl)-3-methylpent-2-enoate

Guidance literature:: With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 0 ℃; Inert atmosphere;
DOI:10.1002/ejoc.201100400

Reference yield:

: 1335013-07-4
(1S,2R,5S)-5-methyl-2-(2-phenylpropan-2-yl)cyclohexyl-2-(diethoxyphosphoryl)-acetate

: 1335013-04-1
(1S,2R,5S)-5-methyl-2-(2-phenylprop-2-yl)cyclohexyl (E)-5-(3,3-dimethyloxiran-2-yl)-3-methylpent-2-enoate

Guidance literature:: Multi-step reaction with 2 steps

1.1: sodium hydride / tetrahydrofuran / 0.12 h / 0 °C / Inert atmosphere

1.2: 4 h / 20 °C / Inert atmosphere

2.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 0 °C / Inert atmosphere

With sodium hydride; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; dichloromethane; 1.1: Wadsworth-Emmons condensation;
DOI:10.1002/ejoc.201100400

Reference yield:

: 57707-91-2
(1S,2R,5S)-8-(+)-phenylmenthol

: 1335013-04-1
(1S,2R,5S)-5-methyl-2-(2-phenylprop-2-yl)cyclohexyl (E)-5-(3,3-dimethyloxiran-2-yl)-3-methylpent-2-enoate

Guidance literature:: Multi-step reaction with 3 steps

1.1: dmap / toluene / 140 h / Reflux; Inert atmosphere

2.1: sodium hydride / tetrahydrofuran / 0.12 h / 0 °C / Inert atmosphere

2.2: 4 h / 20 °C / Inert atmosphere

3.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 0 °C / Inert atmosphere

With dmap; sodium hydride; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; dichloromethane; toluene; 2.1: Wadsworth-Emmons condensation;
DOI:10.1002/ejoc.201100400