dicarbonyl(μ-mercaptothiazolinate)bis{bis(diphenylphosphino)methane}dirhodium chloride * CH2Cl2

Base Information

• Chemical Name: dicarbonyl(μ-mercaptothiazolinate)bis{bis(diphenylphosphino)methane}dirhodium chloride * CH2Cl2
• CAS No.: 150501-37-4
• Molecular Formula: CH₂Cl₂*C₅₅H₄₈NO₂P₄Rh₂S₂*Cl
• Molecular Weight: 1269.22
• Mol file: 150501-37-4.mol

Synonyms:dicarbonyl(μ-mercaptothiazolinate)bis{bis(diphenylphosphino)methane}dirhodium chloride * CH2Cl2

Chemical Property of dicarbonyl(μ-mercaptothiazolinate)bis{bis(diphenylphosphino)methane}dirhodium chloride * CH2Cl2

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of dicarbonyl(μ-mercaptothiazolinate)bis{bis(diphenylphosphino)methane}dirhodium chloride * CH2Cl2

There total 1 articles about dicarbonyl(μ-mercaptothiazolinate)bis{bis(diphenylphosphino)methane}dirhodium chloride * CH2Cl2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

cis-{Rh2Cl2(CO)2(bis(diphenylphosphino)methane)} + sodium 2-mercaptothiazolinate (71591-75-8) → dicarbonyl(μ-mercaptothiazolinate)bis{bis(diphenylphosphino)methane}dirhodium chloride * CH2Cl2 (150501-37-4)

Guidance literature:

With CH₂Cl₂; In tetrahydrofuran; addn. of equimolar amt. NaC3H4NS2 in THF to suspn. of Rh complex; stirring for 5 h;; removal of solvent under vac.; crystn. from CH2Cl2/hexane; elem. anal.;;

Reference yield: 90.0%

silver(I) hexafluorophosphate (26042-63-7) + dicarbonyl(μ-mercaptothiazolinate)bis{bis(diphenylphosphino)methane}dirhodium chloride * CH2Cl2 (150501-37-4) → {dicarbonyl(μ-mercaptothiazolinate)bis(bis(diphenylphosphino)methane)dirhodium}{PF6} (150576-67-3)

Guidance literature:

In dichloromethane; addn. of AgPF6 soln. to soln. of Rh complex; stirring for 0.5 h;; filtering, concg.; addn. of hexane (crystn.); elem. anal.;;

Reference yield:

dicarbonyl(μ-mercaptothiazolinate)bis{bis(diphenylphosphino)methane}dirhodium chloride * CH2Cl2 (150501-37-4) → dicarbonyl(μ-carbonyl)(μ-mercaptothiazolinate)bis(bis(diphenylphosphino)methane)dirhodium chloride

Guidance literature:

With CO; In dichloromethane; passing a stream of CO through soln. of Rh complex; pptn.;;

upstream raw materials:

sodium 2-mercaptothiazolinate

Downstream raw materials:

{dicarbonyl(μ-mercaptothiazolinate)bis(bis(diphenylphosphino)methane)dirhodium}{PF6}