1-diphenylphosphanyl-3-phenyl-1-(2-pyridyl)propane

Base Information

• Chemical Name: 1-diphenylphosphanyl-3-phenyl-1-(2-pyridyl)propane
• CAS No.: 283168-54-7
• Molecular Formula: C₂₆H₂₄NP
• Molecular Weight: 381.457
• Mol file: 283168-54-7.mol

Synonyms:1-diphenylphosphanyl-3-phenyl-1-(2-pyridyl)propane

Chemical Property of 1-diphenylphosphanyl-3-phenyl-1-(2-pyridyl)propane

Chemical Property:

Purity/Quality:

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Technology Process of 1-diphenylphosphanyl-3-phenyl-1-(2-pyridyl)propane

There total 1 articles about 1-diphenylphosphanyl-3-phenyl-1-(2-pyridyl)propane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 20.0%

2-phenylethyl chloride (622-24-2) + 2-diphenylphosphinomethylpyridine (20174-01-0) → 1-diphenylphosphanyl-3-phenyl-1-(2-pyridyl)propane (283168-54-7)

Guidance literature:

With n-butyllithium; In hexane; at 0 ℃; for 2h;

DOI:10.1039/a909262e

Reference yield: 81.0%

ammonium hexafluorophosphate + [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2 (52462-29-0) + dichloromethane (75-09-2) + 1-diphenylphosphanyl-3-phenyl-1-(2-pyridyl)propane (283168-54-7) → [(p-CH3C6H4CH(CH3)2)Ru(1-diphenylphosphanyl-3-phenyl-1-(2-pyridyl)propane)Cl]PF6*CH2Cl2

Guidance literature:

In ethanol; dichloromethane; under N2; CH2Cl2 added to soln. of Ru complex and ethane deriv. in EtOH,stirred at room temp. for 20 h, filtered, filtrate evapd., residue diss olved in MeOH, NH4PF6 added, allowed to stand for 1 h; concd., ppt. filtered off; mixt. of diastereomers obtained; elem. anal.;

DOI:10.1039/a909262e

upstream raw materials:

2-phenylethyl chloride

2-diphenylphosphinomethylpyridine