2-azido-3-O-benzyl-4,6-O-benzylidene-2-deoxy-β-D-glucopyranosyl trichloroacetimidate

Base Information

Chemical Name:2-azido-3-O-benzyl-4,6-O-benzylidene-2-deoxy-β-D-glucopyranosyl trichloroacetimidate
CAS No.:245110-00-3
Molecular Formula:C₂₂H₂₁Cl₃N₄O₅
Molecular Weight:527.792
Hs Code.:

Synonyms:2-azido-3-O-benzyl-4,6-O-benzylidene-2-deoxy-β-D-glucopyranosyl trichloroacetimidate

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Chemical Property of 2-azido-3-O-benzyl-4,6-O-benzylidene-2-deoxy-β-D-glucopyranosyl trichloroacetimidate

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Technology Process of 2-azido-3-O-benzyl-4,6-O-benzylidene-2-deoxy-β-D-glucopyranosyl trichloroacetimidate

There total 2 articles about 2-azido-3-O-benzyl-4,6-O-benzylidene-2-deoxy-β-D-glucopyranosyl trichloroacetimidate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: thexyldimethylsilyl 2-azido-3-O-benzyl-4,6-O-benzylidene-2-deoxy-β-D-glucopyranoside

: 245110-00-3
2-azido-3-O-benzyl-4,6-O-benzylidene-2-deoxy-β-D-glucopyranosyl trichloroacetimidate

Guidance literature:: Multi-step reaction with 2 steps

1: Bu₄NF; AcOH / tetrahydrofuran / 4 h / -40 °C

2: K₂CO₃ / CH₂Cl₂ / 5 h

With tetrabutyl ammonium fluoride; potassium carbonate; acetic acid; In tetrahydrofuran; dichloromethane; 1: desilylation / 2: Addition;
DOI:10.1016/S0040-4020(99)00526-8

Reference yield:

: 545-06-2
trichloroacetonitrile

: 138688-77-4
(2R,4aR,7R,8R,8aS)-7-azido-8-(benzyloxy)-2-phenylhexahydropyrano[3,2-d][1,3]dioxin-6-ol

: 245110-00-3
2-azido-3-O-benzyl-4,6-O-benzylidene-2-deoxy-β-D-glucopyranosyl trichloroacetimidate

Guidance literature:: With potassium carbonate; In dichloromethane; for 5h;
DOI:10.1016/S0040-4020(99)00526-8

Reference yield: 95.0%

: 153996-48-6
2,3:4,5-di-O-cyclohexylidene-1-O-(1R)-menthyloxycarbonyl-D-myo-inositol

: 245110-00-3
2-azido-3-O-benzyl-4,6-O-benzylidene-2-deoxy-β-D-glucopyranosyl trichloroacetimidate

: C₄₉H₆₅N₃O₁₂

Guidance literature:: With trimethylsilyl trifluoromethanesulfonate; MS 4 Angstroem; In diethyl ether; at 25 ℃; for 1h;
DOI:10.1002/(SICI)1099-0690(200004)2000:8<1547::AID-EJOC1547<3.0.CO;2-C