(3aS,4S,6S,7aR)-2-cyclohexyl-3a,5,5-trimethylhexahydro-4,6-methanobenzo[d][1,3,2]dioxaborole

Base Information

Chemical Name:(3aS,4S,6S,7aR)-2-cyclohexyl-3a,5,5-trimethylhexahydro-4,6-methanobenzo[d][1,3,2]dioxaborole
CAS No.:87190-23-6
Molecular Formula:C₁₆H₂₇BO₂
Molecular Weight:262.2
Hs Code.:

Synonyms:(3aS,4S,6S,7aR)-2-cyclohexyl-3a,5,5-trimethylhexahydro-4,6-methanobenzo[d][1,3,2]dioxaborole

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (3aS,4S,6S,7aR)-2-cyclohexyl-3a,5,5-trimethylhexahydro-4,6-methanobenzo[d][1,3,2]dioxaborole

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Technology Process of (3aS,4S,6S,7aR)-2-cyclohexyl-3a,5,5-trimethylhexahydro-4,6-methanobenzo[d][1,3,2]dioxaborole

There total 1 articles about (3aS,4S,6S,7aR)-2-cyclohexyl-3a,5,5-trimethylhexahydro-4,6-methanobenzo[d][1,3,2]dioxaborole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 42.0%

: 953-91-3
cyclohexyl tosylate

: 230299-05-5,230299-17-9
bis((+)-pinanediolato)diboron

: 87190-23-6
(3aS,4S,6S,7aR)-2-cyclohexyl-3a,5,5-trimethylhexahydro-4,6-methanobenzo[d][1,3,2]dioxaborole

Guidance literature:: With silver(I) pentafluoropropionate; lithium tert-butoxide; In 1,4-dioxane; at 60 ℃; for 24h; chemoselective reaction; Schlenk technique; Inert atmosphere;
DOI:10.1002/cjoc.201800500

Reference yield:

: 87190-23-6
(3aS,4S,6S,7aR)-2-cyclohexyl-3a,5,5-trimethylhexahydro-4,6-methanobenzo[d][1,3,2]dioxaborole

: 2146-67-0
(dichloromethyl)lithium

: 87190-39-4
(+)-pinanediol (S)-chloro(cyclohexyl)methaneboronate

Guidance literature:: In tetrahydrofuran; byproducts: LiCl; boronic ester in THF was added to LiCHCl2 in THF at -78°C, a mixture was warmed to 20-25°C and stirred for 12-20 h, inert atm.; diluted whith pentane, filtration, distn.; elem. anal.;