Hexaborane(10)

Base Information

• Chemical Name: Hexaborane(10)
• CAS No.: 23777-80-2
• Molecular Formula: B6H10
• Molecular Weight: 74.9454
• Mol file: 23777-80-2.mol

Synonyms:Boronhydride (B6H10)

Chemical Property of Hexaborane(10)

Chemical Property:

• Melting Point: -62.3°
• Boiling Point: bp 108°
• PSA: 0.00000
• Density: d0 0.69
• LogP: -6.03260
• Water Solubility.: hydrolyzed in H2O if heated [COT88]

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Safety Statements: Ignites spontaneously in air. See also BORANES and BORON COMPOUNDS.:;"> BORANES and BORON COMPOUNDS." target="_blank">Ignites spontaneously in air. See also BORANES and BORON COMPOUNDS.:

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Hexaborane(10)

There total 14 articles about Hexaborane(10) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

lithium borohydride + tetraboron tetrachloride (17156-85-3) → pentaborane(9) (19624-22-7) + hexaborane(10) (23777-80-2)

Guidance literature:

In dibutyl ether; di-n-butyl ether and B4Cl4 were condenced onto a 10-fold excess of LiBH4 and the vessel was sealed and then allowed to warm from -196°C; products were sepd. by fractionation;

Reference yield: 1.0%

diborane (19287-45-7) → nido-decaborane (17702-41-9) + pentaborane(9) (19624-22-7) + hexaborane(10) (23777-80-2) + pentaborane(11) (18433-84-6) + hydrogen (1333-74-0)

Guidance literature:

In neat (no solvent); thermolysis B2H6 at 398-453 K; other products - B6H12, B8H12, and B9H15; Kinetics;

DOI:10.1016/S0022-328X(00)00627-6

Reference yield:

H2B(NH3)2(1+)*B4H7(1-)={H2B(NH3)2}{B4H7} → tetraborane + pentaborane(9) (19624-22-7) + hexaborane(10) (23777-80-2) + hydrogen (1333-74-0) + diborane (19287-45-7)

Guidance literature:

In neat (no solvent); decomposition at 25°C;;

DOI:10.1021/ja00757a017 DOI:10.1021/ja00714a051

upstream raw materials:

diborane

tetraboron tetrachloride

pentaborane⁽⁹⁾

pentaborane⁽¹¹⁾

Downstream raw materials:

nido-decaborane

pentaborane⁽⁹⁾

hydrogen

pentaborane⁽¹¹⁾

Refernces

• 1、 Dodds, Alan R.,Nelson, Mansel A.,Kodama, Goji. "Formation of amine, phosphine, and thioether adducts of chlorotriborane(7)". . p. 4517 - 4521. Retrieved 2008/10/08.
• 2、 Emery,Morrison. "Reactions of tetrachlorotetraborane, B4Cl4, with trimethylstannane, lithium borohydride, and diborane". . p. 1612 - 1613. Retrieved 2008/10/08.