2-cyclohexenyldiethylborane

Base Information

• Chemical Name: 2-cyclohexenyldiethylborane
• CAS No.: 103216-77-9
• Molecular Formula: C₁₀H₁₉B
• Molecular Weight: 150.072
• Mol file: 103216-77-9.mol

Synonyms:2-cyclohexenyldiethylborane

Chemical Property of 2-cyclohexenyldiethylborane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

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Technology Process of 2-cyclohexenyldiethylborane

There total 1 articles about 2-cyclohexenyldiethylborane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

diethylchloroborane (5314-83-0) + potassium (7440-09-7) + bis(trimethylsilylmethyl)mercury (13294-23-0) + cyclohexene (110-83-8) → 2-cyclohexenyldiethylborane (103216-77-9)

Guidance literature:

In diethyl ether; byproducts: KCl, Hg, SiMe4; Ar atmosphere; stirring of K-sand with Hg(CH2Si(CH3)3)2 (in cyclohexane) (1 h), addn. of olefin (excess), stirring (room temp., 48 h), centrifugation, addn. of B-compd. to soln. (-78 ° C), then room temp. (overnight); centrifugation and decantation, distn. of liquid phase; elem. anal.;

DOI:10.1016/0022-328X(85)80282-5

Reference yield: 93.0%

2-cyclohexenyldiethylborane (103216-77-9) → cyclohexene (110-83-8)

Guidance literature:

With sodium hydroxide; water; In water; at 0 ℃; 1.) 1 h 2.) 0.5 h;

DOI:10.1016/0022-328X(85)80282-5

Reference yield: 77.5%

2-cyclohexenyldiethylborane (103216-77-9) → Cyclohex-2-enol (822-67-3)

Guidance literature:

With dihydrogen peroxide; trimethylamine; In tetrahydrofuran; water; for 2h; Ambient temperature;

DOI:10.1016/0022-328X(85)80282-5

upstream raw materials:

diethylchloroborane

potassium

bis(trimethylsilylmethyl)mercury

cyclohexene

Downstream raw materials:

(S)-(S)-1-Cyclohex-2-enyl-ethanol

Cyclohex-2-enol

cyclohexene

1-acetyl-2-cyclohexene

Refernces