2,3,5-tri-O-benzyl-1,4-dideoxy-1,4-imino-N-benzyl-L-xylitol

Base Information

• Chemical Name: 2,3,5-tri-O-benzyl-1,4-dideoxy-1,4-imino-N-benzyl-L-xylitol
• CAS No.: 134307-35-0
• Molecular Formula: C₃₃H₃₅NO₃
• Molecular Weight: 493.646
• Mol file: 134307-35-0.mol

Synonyms:2,3,5-tri-O-benzyl-1,4-dideoxy-1,4-imino-N-benzyl-L-xylitol

Chemical Property of 2,3,5-tri-O-benzyl-1,4-dideoxy-1,4-imino-N-benzyl-L-xylitol

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,3,5-tri-O-benzyl-1,4-dideoxy-1,4-imino-N-benzyl-L-xylitol

There total 12 articles about 2,3,5-tri-O-benzyl-1,4-dideoxy-1,4-imino-N-benzyl-L-xylitol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

C28H34O9S2 (260551-24-4) + benzylamine (100-46-9) → 2,3,5-tri-O-benzyl-1,4-dideoxy-1,4-imino-N-benzyl-L-xylitol (134307-35-0)

Guidance literature:

at 120 ℃; for 0.333333h; Microwave irradiation;

DOI:10.1016/j.tetlet.2009.06.062

Reference yield: 44.0%

(3S,4R)-1,3,4-tris(benzyloxy)-hex-5-en-2-one (220939-94-6) + benzylamine (100-46-9) → 2,3,5-tri-O-benzyl-1,4-benzylimino-1,4-dideoxy-D-arabinitol (909801-43-0) + 2,3,5-tri-O-benzyl-1,4-dideoxy-1,4-imino-N-benzyl-L-xylitol (134307-35-0)

Guidance literature:

(3S,4R)-1,3,4-tris(benzyloxy)-hex-5-en-2-one; With ozone; In methanol; dichloromethane; at -78 ℃; for 0.5h;

With dimethylsulfide; In methanol; dichloromethane; at -78 - 20 ℃;

benzylamine; With 3 A molecular sieve; sodium cyanoborohydride; acetic acid; In tetrahydrofuran; at 20 ℃; pH=6 - 7; Further stages.;

DOI:10.1039/b605818c

Reference yield: 33.0%

1-N,2-O,3-O,5-O-tetrabenzyl-4-O-mesyl-D-arabinonamide (134307-33-8) → 2,3,5-tri-O-benzyl-1,4-dideoxy-1,4-imino-N-benzyl-L-xylitol (134307-35-0)

Guidance literature:

With dimethylsulfide borane complex; In tetrahydrofuran; toluene; at 130 ℃; for 5h;

DOI:10.1002/hlca.19910740222

upstream raw materials:

1-N,2-O,3-O,5-O-tetrabenzyl-4-O-mesyl-D-arabinonamide

2,3,5-tri-O-benzyl-1-(benzylamino)-1-deoxy-D-arabitol

methanesulfonyl chloride

(3S,4R)-1,3,4-tris(benzyloxy)-hex-5-en-2-one