(2R)-9-[1-(tert-butyl)-1,1-dimethylsilyl]oxy-1-[(4-methoxybenzyl)oxy]-4-nonyn-2-ol

Base Information

Chemical Name:(2R)-9-[1-(tert-butyl)-1,1-dimethylsilyl]oxy-1-[(4-methoxybenzyl)oxy]-4-nonyn-2-ol
CAS No.:1252798-65-4
Molecular Formula:C₂₃H₃₈O₄Si
Molecular Weight:406.638
Hs Code.:

Synonyms:(2R)-9-[1-(tert-butyl)-1,1-dimethylsilyl]oxy-1-[(4-methoxybenzyl)oxy]-4-nonyn-2-ol

Suppliers and Price of (2R)-9-[1-(tert-butyl)-1,1-dimethylsilyl]oxy-1-[(4-methoxybenzyl)oxy]-4-nonyn-2-ol

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (2R)-9-[1-(tert-butyl)-1,1-dimethylsilyl]oxy-1-[(4-methoxybenzyl)oxy]-4-nonyn-2-ol

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Technology Process of (2R)-9-[1-(tert-butyl)-1,1-dimethylsilyl]oxy-1-[(4-methoxybenzyl)oxy]-4-nonyn-2-ol

There total 1 articles about (2R)-9-[1-(tert-butyl)-1,1-dimethylsilyl]oxy-1-[(4-methoxybenzyl)oxy]-4-nonyn-2-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 73448-13-2
tert-butyldimethylsilyl hex-5-yn-1-yl ether

: 80910-01-6,108836-41-5,144069-33-0,134733-19-0
(R)-2-(((4-methoxybenzyl)oxy)methyl)oxirane

: 1252798-65-4
(2R)-9-[1-(tert-butyl)-1,1-dimethylsilyl]oxy-1-[(4-methoxybenzyl)oxy]-4-nonyn-2-ol

Guidance literature:: tert-butyldimethylsilyl hex-5-yn-1-yl ether; With n-butyllithium; In tetrahydrofuran; hexane; at -78 - 0 ℃; Inert atmosphere;

(R)-2-(((4-methoxybenzyl)oxy)methyl)oxirane; With boron trifluoride diethyl etherate; In tetrahydrofuran; hexane; at -78 ℃; Inert atmosphere;
DOI:10.1002/ejoc.201000565

Reference yield: 97.0%

: 1252798-65-4
(2R)-9-[1-(tert-butyl)-1,1-dimethylsilyl]oxy-1-[(4-methoxybenzyl)oxy]-4-nonyn-2-ol

: 58479-61-1
tert-butylchlorodiphenylsilane

: 1252798-79-0
tert-butyl {(8R)-8-[1-(tert-butyl)-1,1-diphenylsilyl]oxy-9-[(4-methoxybenzyl)oxy]-5-nonynyloxy}dimethylsilane

Guidance literature:: With 1H-imidazole; In N,N-dimethyl-formamide; at 0 - 20 ℃; for 12h; Inert atmosphere;
DOI:10.1002/ejoc.201000565

Reference yield:

: 1252798-65-4
(2R)-9-[1-(tert-butyl)-1,1-dimethylsilyl]oxy-1-[(4-methoxybenzyl)oxy]-4-nonyn-2-ol

: 100-39-0
benzyl bromide

: 1252798-66-5
{(8R)-8-(benzyloxy)-9-[(4-methoxybenzyl)oxy]-5-nonynyloxy}(tert-butyl)dimethylsilane

Guidance literature:: (2R)-9-[1-(tert-butyl)-1,1-dimethylsilyl]oxy-1-[(4-methoxybenzyl)oxy]-4-nonyn-2-ol; With sodium hydride; In tetrahydrofuran; mineral oil; at 0 - 20 ℃; for 1h; Inert atmosphere;

benzyl bromide; In tetrahydrofuran; mineral oil; at 20 ℃; for 4h; Inert atmosphere;
DOI:10.1002/ejoc.201000565