Methyl-undec-9-enoate

Base Information

• Chemical Name: Methyl-undec-9-enoate
• CAS No.: 5760-50-9
• Molecular Formula: C12H22 O2
• Molecular Weight: 198.305
• Mol file: 5760-50-9.mol

Synonyms:methyl-undec-9-enoate;SCHEMBL872716

Chemical Property of Methyl-undec-9-enoate

Chemical Property:

• Vapor Pressure: 0.019mmHg at 25°C
• Refractive Index: 1.4460 (estimate)
• Boiling Point: 252.8°C at 760 mmHg
• Flash Point: 84.3°C
• PSA: 26.30000
• Density: 0.886g/cm³
• LogP: 3.46620
• XLogP3: 3.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 9
• Exact Mass: 198.161979940
• Heavy Atom Count: 14
• Complexity: 162

Purity/Quality:

99% ^*data from raw suppliers

METHYL UNDECYLENATE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC=CCCCCCCCC(=O)OC
• Description: Methyl 9-undecenoate has a sweet, persistent, light, fatty, green odor reminiscent of wine and iron. It has a brandy-like flavor at low concentrations. It is unpleasant at high levels. May be prepared by direct esterification of the acid with methanol and concentrated H2S04 or HCl; by thermal decomposition of methyl ricinoleate.

Technology Process of Methyl-undec-9-enoate

There total 33 articles about Methyl-undec-9-enoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

propene (187737-37-7,13987-01-4,15220-87-8,9003-07-0,676-63-1,25085-53-4) + soy fatty acid methyl ester → 1-Decene (872-05-9,17438-89-0,25189-70-2) + 2-undecene (2244-02-2) + methyl 9-decenoate (25601-41-6) + methyl 9‐undecenoate (5760-50-9)

Guidance literature:

1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene-dichloro(3-methyl-2-buteneylidene)-(tricyclohexylphosphine)ruthenium; In dichloromethane; at 60 ℃; for 4h; under 6723.1 - 7757.43 Torr; Product distribution / selectivity;

Reference yield:

methyl soyate + propene (187737-37-7,13987-01-4,15220-87-8,9003-07-0,676-63-1,25085-53-4) → 1-Decene (872-05-9,17438-89-0,25189-70-2) + 2-undecene (2244-02-2) + methyl 9-decenoate (25601-41-6) + methyl 9‐undecenoate (5760-50-9)

Guidance literature:

[1,3-bis-(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro(3-methyl-2-butenylidene)(tricyclohexylphosphine)ruthenium(II); at 60 ℃; for 4.5h; under 6723.1 - 7757.43 Torr; Product distribution / selectivity;

Reference yield:

propene (187737-37-7,13987-01-4,15220-87-8,9003-07-0,676-63-1,25085-53-4) + canola FAME → 1-Decene (872-05-9,17438-89-0,25189-70-2) + 2-undecene (2244-02-2) + methyl 9-decenoate (25601-41-6) + methyl 9‐undecenoate (5760-50-9)

Guidance literature:

[1,3-bis-(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro(3-methyl-2-butenylidene)(tricyclohexylphosphine)ruthenium(II); In dichloromethane; at 60 ℃; for 2 - 4h; under 6723.1 Torr; Product distribution / selectivity;

upstream raw materials:

propene

soybean oil

Methyl 10-undecenoate