2244-02-2

Basic information

• Product Name: hendecene
• Synonyms: hendecene;undecylene;2-Undecene
• CAS NO: 2244-02-2
• Molecular Formula: C₁₁H₂₂
• Molecular Weight: 154.2924
• Mol File: 2244-02-2.mol
• Article Data: 11

Chemical Properties

• Melting Point: -67.3°C (estimate)
• Boiling Point: 187.71°C (estimate)
• Flash Point: 61.2°C
• Appearance: /
• Density: 0.7709 (estimate)
• Vapor Pressure: 0.569mmHg at 25°C
• Refractive Index: 1.4224 (estimate)
• CAS DataBase Reference: hendecene(CAS DataBase Reference)
• NIST Chemistry Reference: hendecene(2244-02-2)
• EPA Substance Registry System: hendecene(2244-02-2)

Safety Data

• Hazardous Substances Data: 2244-02-2(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Tetrahedron Letters, 23, p. 3411, 1982 DOI: 10.1016/S0040-4039(00)87629-7

InChI:InChI=1/C11H22/c1-3-5-7-9-11-10-8-6-4-2/h3,5H,4,6-11H2,1-2H3

Upstream product

• 1653-30-1 undecan-2-ol 
• 7664-93-9 sulfuric acid 
• 112-12-9 methyl nonyl ketone 
• 56956-46-8 undeca-1,2-diene 
• 124-41-4 sodium methylate 
• 187737-37-7 propene 
• 694-53-1 phenylsilane 
• 513-35-9 2-methyl-but-2-ene 
• 2462-84-2 methyl (9E)-octadec-9-enoate 
• 107-01-7 butene-2 
• 112-62-9 Methyl oleate 
• 821-95-4 1-undecene 
• 201230-82-2 carbon monoxide 

Downstream Products

• 1120-21-4 n-Undecane 
• 2243-98-3 1-undecyne 
• 112-05-0 nonanoic acid 

Relevant articles and documents

Chelating Ruthenium Phenolate Complexes: Synthesis, General Catalytic Activity, and Applications in Olefin Metathesis Polymerization

Cyclic Ru-phenolates were synthesized, and these compounds were used as olefin metathesis catalysts. Investigation of their catalytic activity pointed out that, after activation with chemical agents, these catalysts promote ring-closing metathesis (RCM), enyne and cross-metathesis (CM) reactions, including butenolysis, with good results. Importantly, these latent catalysts are soluble in neat dicyclopentadiene (DCPD) and show good applicability in ring-opening metathesis polymeriyation (ROMP) of this monomer. Olefin metathesis catalysis: Investigation of the catalytic activity of Ru phenolate catalysts pointed out that, after activation with chemical agents, these catalysts promote ring-closing metathesis (RCM), enyne, and cross-metathesis (CM) reactions, including butenolysis, with good results (see scheme, Mes=2,4,6-trimethylphenyl, Cy=cyclohexyl). The phenolanate catalysts, well soluble in dicyclopentadiene (DCPD), also show good applicability in ring-opening metathesis polymerization (ROMP) of this monomer.

Fishing for the right catalyst for the cross-metathesis reaction of methyl oleate with 2-methyl-2-butene

The activity of various Ru-alkylidene olefin metathesis catalyst types on the outcome of cross-metathesis of methyl oleate with 2-methyl-2-butene was studied.

Hydroindation of allenes and its application to radical cyclization

Hydroindation of allenes and radical cyclization of 1,2,7-trienes (allenenes) were accomplished by HInCl2 with high regioselectivity to afford a variety of cyclic compounds. The resulting vinylic indiums could be used for successive coupling reactions in a one-pot procedure. The use of HInCl2 generated slowly in situ is extremely effective for the radical cyclization. The Royal Society of Chemistry.