2-methyl-3-phenyl-2H-azirene

Base Information

• Chemical Name: 2-methyl-3-phenyl-2H-azirene
• CAS No.: 16205-14-4
• Molecular Formula: C9H9 N
• Molecular Weight: 131.177
• Mol file: 16205-14-4.mol

Synonyms:2-Methyl-3-phenyl-2H-azirine;3-Methyl-2-phenyl-1-azirine; NSC 208904

Chemical Property of 2-methyl-3-phenyl-2H-azirene

Chemical Property:

• Vapor Pressure: 0.493mmHg at 25°C
• Boiling Point: 199°C at 760 mmHg
• Flash Point: 65.5°C
• Density: 1.05g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-methyl-3-phenyl-2H-azirene

There total 11 articles about 2-methyl-3-phenyl-2H-azirene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

β-methyl-α-azidostyrene → 2-Methyl-3-phenyl-2H-azirine (16205-14-4)

Guidance literature:

In chloroform; for 10h; Inert atmosphere; Photolysis;

DOI:10.1021/jo402443w

Reference yield: 85.0%

(Z)-(1-azidoprop-1-enyl)benzene → 2-Methyl-3-phenyl-2H-azirine (16205-14-4)

Guidance literature:

for 3h; microwave irradiation;

DOI:10.1016/S0040-4039(03)01558-2

Reference yield: 61.0%

2-Ethyl-3-(3-methyl-2-phenyl-2-trimethylsilanyl-aziridin-1-yl)-3H-quinazolin-4-one → 2-ethyl-3H-quinazolin-4-one (3137-64-2) + 2-Methyl-3-phenyl-2H-azirine (16205-14-4)

Guidance literature:

With cesium fluoride; In N,N-dimethyl-formamide; for 5h; Ambient temperature;

DOI:10.1039/c39890000836

upstream raw materials:

(1-azido-2-iodopropyl)benzene

1-propenylbenzene

1-phenylpropene

propiophenone oxime

Downstream raw materials:

2,4-dibenzhydrylidene-7-methyl-6-phenyl-3,5-dioxa-1-aza-bicyclo[4.1.0]heptane

2,4-dibenzhydrylidene-7c-methyl-6-phenyl-(6rH)-3,5-dioxa-1-aza-bicyclo[4.1.0]heptane

4-methyl-5-phenyl-N-(pyridin-2-yl)thiazol-2-amine

3,3,3',3'-tetramethyl-2,2'-(7c-methyl-6-phenyl-(6rH)-3,5-dioxa-1-aza-bicyclo[4.1.0]heptane-2,4-diylidene)-bis-butyronitrile