Technology Process of (E)-tert-butyldiphenyl((16-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)hexadec-15-en-1-yl)oxy)silane
There total 9 articles about (E)-tert-butyldiphenyl((16-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)hexadec-15-en-1-yl)oxy)silane which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
chromium dichloride; manganese; chloro-trimethyl-silane; lithium iodide;
In
tetrahydrofuran;
at 20 ℃;
for 16.5h;
Inert atmosphere;
DOI:10.1021/tx300315h
- Guidance literature:
-
Multi-step reaction with 6 steps
1.1: hydrogen bromide / toluene
2.1: triphenylphosphine / acetonitrile / 90 h / Reflux
3.1: n-butyllithium / hexane; tetrahydrofuran / 0.17 h / 0 °C / Inert atmosphere
3.2: 0.17 h / 0 °C / Inert atmosphere
4.1: palladium 10% on activated carbon; hydrogen / methanol / 2 h / 20 °C
5.1: dimethyl sulfoxide; oxalyl dichloride / dichloromethane / 0.33 h / -78 °C / Inert atmosphere
5.2: 0.5 h / -78 - 20 °C / Inert atmosphere
6.1: chloro-trimethyl-silane; chromium dichloride; lithium iodide; manganese / tetrahydrofuran / 16.5 h / 20 °C / Inert atmosphere
With
chromium dichloride; manganese; n-butyllithium; chloro-trimethyl-silane; oxalyl dichloride; palladium 10% on activated carbon; hydrogen bromide; hydrogen; dimethyl sulfoxide; triphenylphosphine; lithium iodide;
In
tetrahydrofuran; methanol; hexane; dichloromethane; toluene; acetonitrile;
DOI:10.1021/tx300315h
- Guidance literature:
-
Multi-step reaction with 5 steps
1.1: dimethyl sulfoxide; oxalyl dichloride / dichloromethane / 0.33 h / -78 °C / Inert atmosphere
1.2: 0.5 h / -78 - 20 °C / Inert atmosphere
2.1: n-butyllithium / hexane; tetrahydrofuran / 0.17 h / 0 °C / Inert atmosphere
2.2: 0.17 h / 0 °C / Inert atmosphere
3.1: palladium 10% on activated carbon; hydrogen / methanol / 2 h / 20 °C
4.1: dimethyl sulfoxide; oxalyl dichloride / dichloromethane / 0.33 h / -78 °C / Inert atmosphere
4.2: 0.5 h / -78 - 20 °C / Inert atmosphere
5.1: chloro-trimethyl-silane; chromium dichloride; lithium iodide; manganese / tetrahydrofuran / 16.5 h / 20 °C / Inert atmosphere
With
chromium dichloride; manganese; n-butyllithium; chloro-trimethyl-silane; oxalyl dichloride; palladium 10% on activated carbon; hydrogen; dimethyl sulfoxide; lithium iodide;
In
tetrahydrofuran; methanol; hexane; dichloromethane;
DOI:10.1021/tx300315h
