10,10'-dihydroxy-10,10'-bis(2,4,6-trimethylphenyl)-9,9'-bianthracenylidene

Base Information

• Chemical Name: 10,10'-dihydroxy-10,10'-bis(2,4,6-trimethylphenyl)-9,9'-bianthracenylidene
• CAS No.: 1191886-63-1
• Molecular Formula: C₄₆H₄₀O₂
• Molecular Weight: 624.822
• Mol file: 1191886-63-1.mol

Synonyms:10,10'-dihydroxy-10,10'-bis(2,4,6-trimethylphenyl)-9,9'-bianthracenylidene

Chemical Property of 10,10'-dihydroxy-10,10'-bis(2,4,6-trimethylphenyl)-9,9'-bianthracenylidene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 10,10'-dihydroxy-10,10'-bis(2,4,6-trimethylphenyl)-9,9'-bianthracenylidene

There total 1 articles about 10,10'-dihydroxy-10,10'-bis(2,4,6-trimethylphenyl)-9,9'-bianthracenylidene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

1-bromo-2,4,6-tri-tert-butylbenzene (3975-77-7) + bianthrone (434-85-5) → 10,10'-dihydroxy-10,10'-bis(2,4,6-trimethylphenyl)-9,9'-bianthracenylidene (1191886-63-1)

Guidance literature:

1-bromo-2,4,6-tri-tert-butylbenzene; With tert.-butyl lithium; In tetrahydrofuran; pentane; at -78 - -15 ℃; for 3h; Inert atmosphere;

bianthrone; In tetrahydrofuran; pentane; at -78 - 20 ℃; for 4h; Inert atmosphere;

DOI:10.1021/ja907802g

Reference yield: 41.0%

10,10'-dihydroxy-10,10'-bis(2,4,6-trimethylphenyl)-9,9'-bianthracenylidene (1191886-63-1) → 10,10'-bis(2,4,6-trimethylphenyl)bianthracene (1191886-66-4) + 7,14-dimesitylphenanthro[1,10,9,8-opqra]perylene (1191886-64-2)

Guidance literature:

10,10'-dihydroxy-10,10'-bis(2,4,6-trimethylphenyl)-9,9'-bianthracenylidene; With iodine; In benzene; for 4h; 450 W medium pressure mercury lamp; Inert atmosphere;

With potassium; In tetrahydrofuran; at 90 ℃; for 48h; sealed vessel; Inert atmosphere;

DOI:10.1021/ja907802g

Reference yield: 18.0%

10,10'-dihydroxy-10,10'-bis(2,4,6-trimethylphenyl)-9,9'-bianthracenylidene (1191886-63-1) → 10,10'-bis(2,4,6-trimethylphenyl)bianthracene (1191886-66-4) + 7,16-bis(2,4,6-trimethylphenyl)dibenzo[a,o]perylene (1191886-65-3) + 7,14-dimesitylphenanthro[1,10,9,8-opqra]perylene (1191886-64-2)

Guidance literature:

With iodine; In benzene; for 4h; 450 W medium pressure mercury lamp; Inert atmosphere;

DOI:10.1021/ja907802g

upstream raw materials:

1-bromo-2,4,6-tri-tert-butylbenzene

bianthrone

Downstream raw materials:

10,10'-bis(2,4,6-trimethylphenyl)bianthracene

7,16-bis(2,4,6-trimethylphenyl)dibenzo[a,o]perylene

7,14-dimesitylphenanthro[1,10,9,8-opqra]perylene