O²-(2,4-dinitrophenyl) 1-[2-(hydroxymethyl)pyrrolidin-1-yl]diazen-1-ium-1,2-diolate

Base Information

• Chemical Name: O²-(2,4-dinitrophenyl) 1-[2-(hydroxymethyl)pyrrolidin-1-yl]diazen-1-ium-1,2-diolate
• CAS No.: 949888-32-8
• Molecular Formula: C₁₁H₁₃N₅O₇
• Molecular Weight: 327.254

Synonyms:O²-(2,4-dinitrophenyl) 1-[2-(hydroxymethyl)pyrrolidin-1-yl]diazen-1-ium-1,2-diolate

Chemical Property of O²-(2,4-dinitrophenyl) 1-[2-(hydroxymethyl)pyrrolidin-1-yl]diazen-1-ium-1,2-diolate

Chemical Property:

Purity/Quality:

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Technology Process of O²-(2,4-dinitrophenyl) 1-[2-(hydroxymethyl)pyrrolidin-1-yl]diazen-1-ium-1,2-diolate

There total 3 articles about O²-(2,4-dinitrophenyl) 1-[2-(hydroxymethyl)pyrrolidin-1-yl]diazen-1-ium-1,2-diolate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 54.0%

(S,Z)-2-hydroxy-1-(2-(hydroxymethyl)pyrrolidin-1-yl)diazene oxide sodium salt + 2,4-Dinitrofluorobenzene (70-34-8,65727-75-5) → O2-(2,4-dinitrophenyl) 1-[2-(hydroxymethyl)pyrrolidin-1-yl]diazen-1-ium-1,2-diolate (949888-32-8)

Guidance literature:

With sodium hydrogencarbonate; In water; tert-butyl alcohol; at 20 ℃;

DOI:10.1021/ol701419a

Reference yield:

(S)-1-[2-(hydroxymethyl)pyrrolidin-1-yl]diazen-1-ium-1,2-diolate sodium salt (949888-30-6,1177456-95-9) + 1-chloro-2,4-dinitro-benzene (97-00-7) → O2-(2,4-dinitrophenyl) 1-(2-(hydroxymethyl)pyrrolidin-1-yl)diazen-1-ium-1,2-diolate (949888-32-8)

Guidance literature:

In N,N-dimethyl-formamide;

Reference yield:

(S)-1-Pyrrolidin-2-yl-methanol (23356-96-9) → O2-(2,4-dinitrophenyl) 1-[2-(hydroxymethyl)pyrrolidin-1-yl]diazen-1-ium-1,2-diolate (949888-32-8)

Guidance literature:

Multi-step reaction with 2 steps

1: 73 percent / sodium methoxide; nitric oxide / methanol; diethyl ether / 6 h / 3102.97 Torr

2: 54 percent / NaHCO₃ / 2-methyl-propan-2-ol; H₂O / 20 °C

With nitric oxide; sodium methylate; sodium hydrogencarbonate; In methanol; diethyl ether; water; tert-butyl alcohol;

DOI:10.1021/ol701419a

upstream raw materials:

2,4-Dinitrofluorobenzene

(S)-1-Pyrrolidin-2-yl-methanol

(S)-1-[2-(hydroxymethyl)pyrrolidin-1-yl]diazen-1-ium-1,2-diolate sodium salt

1-chloro-2,4-dinitro-benzene

Downstream raw materials:

C₁₁H₁₁N₅O₈

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