1,11-bis[(4-methylphenyl)sulfonyl]-7-tridecyl-1,4,8,11-tetraazacycloheptadecan-5-one

Base Information

Chemical Name:1,11-bis[(4-methylphenyl)sulfonyl]-7-tridecyl-1,4,8,11-tetraazacycloheptadecan-5-one
CAS No.:544696-93-7
Molecular Formula:C₄₀H₆₆N₄O₅S₂
Molecular Weight:747.12
Hs Code.:

Synonyms:1,11-bis[(4-methylphenyl)sulfonyl]-7-tridecyl-1,4,8,11-tetraazacycloheptadecan-5-one

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Chemical Property of 1,11-bis[(4-methylphenyl)sulfonyl]-7-tridecyl-1,4,8,11-tetraazacycloheptadecan-5-one

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Technology Process of 1,11-bis[(4-methylphenyl)sulfonyl]-7-tridecyl-1,4,8,11-tetraazacycloheptadecan-5-one

There total 14 articles about 1,11-bis[(4-methylphenyl)sulfonyl]-7-tridecyl-1,4,8,11-tetraazacycloheptadecan-5-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

: 544696-92-6
ethyl 16-amino-7,14-bis[(4-methylphenyl)sulfonyl]-3-tridecyl-4,7,14-triazahexadecanoate

: 544696-93-7
1,11-bis[(4-methylphenyl)sulfonyl]-7-tridecyl-1,4,8,11-tetraazacycloheptadecan-5-one

Guidance literature:: triethoxyantimony; In benzene; for 24h; Heating;
DOI:10.1002/hlca.200390033

Reference yield: 55.0%

: 4239-24-1
1,6-hexanediol dimethanesulfonate

: 544697-00-9
N-{2-{[(4-methylphenyl)sulfonyl]amino}ethyl}-3-{{2-{[(4-methylphenyl)sulfonyl]amino}ethyl}amino}hexadecanamide

: 544696-93-7
1,11-bis[(4-methylphenyl)sulfonyl]-7-tridecyl-1,4,8,11-tetraazacycloheptadecan-5-one

Guidance literature:: N-{2-{[(4-methylphenyl)sulfonyl]amino}ethyl}-3-{{2-{[(4-methylphenyl)sulfonyl]amino}ethyl}amino}hexadecanamide; caesium carbonate; In N,N-dimethyl-formamide; at 60 ℃; for 0.25h;

1,6-hexanediol dimethanesulfonate; In N,N-dimethyl-formamide; at 40 ℃; for 24h;
DOI:10.1002/hlca.200390033

Reference yield:

: 124-09-4
1,6-Hexanediamine

: 544696-93-7
1,11-bis[(4-methylphenyl)sulfonyl]-7-tridecyl-1,4,8,11-tetraazacycloheptadecan-5-one

Guidance literature:: Multi-step reaction with 6 steps

1: 71 percent / KF/Celite / acetonitrile / 48 h / 20 °C

2: 90 percent / Et₃N / CH₂Cl₂ / 12 h / 20 °C

3: 95 percent / H₂; NH₄OH / Raney-Ni / ethanol; H₂O / 20 h / 20 °C / 2844.31 Torr

4: 63 percent / ethanol / 2 h / Heating

5: 90 percent / H₂ / PtO₂ / CHCl₃; ethanol / 4 h / 20 °C / 2844.31 Torr

6: 60 percent / Sb(OEt)3 / benzene / 24 h / Heating

With ammonium hydroxide; hydrogen; triethylamine; platinum(IV) oxide; potassium fluoride; Celite; triethoxyantimony; nickel; In ethanol; dichloromethane; chloroform; water; acetonitrile; benzene; 4: Michael addition / 6: Yamamoto cyclization;
DOI:10.1002/hlca.200390033