N-cyclohexyl-1,7-bis(pyrrolidin-1-yl)perylene-3,4:9,10-tetracarboxylic acid 3,4-anhydride 9,10-imide

Base Information

• Chemical Name: N-cyclohexyl-1,7-bis(pyrrolidin-1-yl)perylene-3,4:9,10-tetracarboxylic acid 3,4-anhydride 9,10-imide
• CAS No.: 404871-18-7
• Molecular Formula: C₃₈H₃₃N₃O₅
• Molecular Weight: 611.697
• Mol file: 404871-18-7.mol

Synonyms:N-cyclohexyl-1,7-bis(pyrrolidin-1-yl)perylene-3,4:9,10-tetracarboxylic acid 3,4-anhydride 9,10-imide

Chemical Property of N-cyclohexyl-1,7-bis(pyrrolidin-1-yl)perylene-3,4:9,10-tetracarboxylic acid 3,4-anhydride 9,10-imide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N-cyclohexyl-1,7-bis(pyrrolidin-1-yl)perylene-3,4:9,10-tetracarboxylic acid 3,4-anhydride 9,10-imide

There total 5 articles about N-cyclohexyl-1,7-bis(pyrrolidin-1-yl)perylene-3,4:9,10-tetracarboxylic acid 3,4-anhydride 9,10-imide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

N,N′-dicyclohexyl-1,7-dipyrrolidinylperylene-3,4:9,10-tetracarboxylic acid bisimide (249733-87-7) → N-cyclohexyl-1,7-bis(pyrrolidin-1-yl)perylene-3,4:9,10-tetracarboxylic acid 3,4-anhydride 9,10-imide (404871-18-7)

Guidance literature:

With potassium hydroxide; In water; isopropyl alcohol; for 2.75h; Heating;

DOI:10.1021/jo048880d

Reference yield:

C38H35N3O6 → N-cyclohexyl-1,7-bis(pyrrolidin-1-yl)perylene-3,4:9,10-tetracarboxylic acid 3,4-anhydride 9,10-imide (404871-18-7)

Guidance literature:

With acetic acid; at 20 ℃; for 0.25h;

DOI:10.1002/anie.200703749

Reference yield:

cyclohexylamine (108-91-8,157973-60-9) → N-cyclohexyl-1,7-bis(pyrrolidin-1-yl)perylene-3,4:9,10-tetracarboxylic acid 3,4-anhydride 9,10-imide (404871-18-7)

Guidance literature:

Multi-step reaction with 3 steps

1.1: Br₂; I₂; H₂SO₄ / 18 h / 85 °C

1.2: 22 percent / H₂O; propan-1-ol / 10 h / 80 °C

2.1: 67 percent / 24 h / Heating

3.1: 88 percent / KOH / propan-2-ol; H₂O / 2.75 h / Heating

With potassium hydroxide; sulfuric acid; bromine; iodine; In water; isopropyl alcohol;

DOI:10.1021/jo048880d

upstream raw materials:

N,N′-dicyclohexyl-1,7-dipyrrolidinylperylene-3,4:9,10-tetracarboxylic acid bisimide

cyclohexylamine

perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride

N,N'-dicyclohexyl-1,7-dibromoperylene-3,4:9,10-tetracarboxylic dianhydride

Downstream raw materials:

C₈₂H₆₅N₉O₈