(1R,2S,3S,3'R,4S)-2-(3-hydroxy-3-cyclohexyl-1(E)-propenyl)-3(E/Z)-methoxyvinyl-7-oxabicyclo<2.2.1>heptane

Base Information

• Chemical Name: (1R,2S,3S,3'R,4S)-2-(3-hydroxy-3-cyclohexyl-1(E)-propenyl)-3(E/Z)-methoxyvinyl-7-oxabicyclo<2.2.1>heptane
• CAS No.: 171230-45-8
• Molecular Formula: C₁₈H₂₈O₃
• Molecular Weight: 292.419
• Mol file: 171230-45-8.mol

Synonyms:(1R,2S,3S,3'R,4S)-2-(3-hydroxy-3-cyclohexyl-1(E)-propenyl)-3(E/Z)-methoxyvinyl-7-oxabicyclo<2.2.1>heptane

Chemical Property of (1R,2S,3S,3'R,4S)-2-(3-hydroxy-3-cyclohexyl-1(E)-propenyl)-3(E/Z)-methoxyvinyl-7-oxabicyclo<2.2.1>heptane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (1R,2S,3S,3'R,4S)-2-(3-hydroxy-3-cyclohexyl-1(E)-propenyl)-3(E/Z)-methoxyvinyl-7-oxabicyclo<2.2.1>heptane

There total 1 articles about (1R,2S,3S,3'R,4S)-2-(3-hydroxy-3-cyclohexyl-1(E)-propenyl)-3(E/Z)-methoxyvinyl-7-oxabicyclo<2.2.1>heptane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 48.4%

(1R,2S,3S,4S)-2-(3-oxo-3-cyclohexyl-1(E)-propenyl)-3-(E/Z)-methoxyvinyl-7-oxabicyclo<2.2.1>-heptane → (1R,2S,3S,3'R,4S)-2-(3-hydroxy-3-cyclohexyl-1(E)-propenyl)-3(E/Z)-methoxyvinyl-7-oxabicyclo<2.2.1>heptane (171230-45-8) + (1R,2S,3S,3'S,4S)-2-(3-hydroxy-3-cyclohexyl-1(E)-propenyl)-3(E/Z)-methoxyvinyl-7-oxabicyclo<2.2.1>heptane

Guidance literature:

With sodium tetrahydroborate; cerium(III) chloride; In methanol; at 0 ℃; for 0.116667h;

DOI:10.1016/0040-4020(95)00619-J

Reference yield:

(1R,2S,3S,3'R,4S)-2-(3-hydroxy-3-cyclohexyl-1(E)-propenyl)-3(E/Z)-methoxyvinyl-7-oxabicyclo<2.2.1>heptane (171230-45-8) → [(1S,2S,3S,4R)-3-((E)-(R)-3-Cyclohexyl-3-hydroxy-propenyl)-7-oxa-bicyclo[2.2.1]hept-2-yl]-acetaldehyde

Guidance literature:

With hydrogenchloride; In tetrahydrofuran; for 6h; Ambient temperature;

DOI:10.1016/0040-4020(95)00619-J

Reference yield:

methanol (67-56-1) + (1R,2S,3S,3'R,4S)-2-(3-hydroxy-3-cyclohexyl-1(E)-propenyl)-3(E/Z)-methoxyvinyl-7-oxabicyclo<2.2.1>heptane (171230-45-8) → (E)-(R)-1-Cyclohexyl-3-[(1R,2S,3S,4S)-3-(2,2-dimethoxy-ethyl)-7-oxa-bicyclo[2.2.1]hept-2-yl]-prop-2-en-1-ol

Guidance literature:

With toluene-4-sulfonic acid; In dichloromethane;

DOI:10.1016/0040-4020(95)00619-J