4,4'-bis{[(2''-benzylaminoformyl)phenoxy]methyl}-1,1'-biphenyl

Base Information

• Chemical Name: 4,4'-bis{[(2''-benzylaminoformyl)phenoxy]methyl}-1,1'-biphenyl
• CAS No.: 896102-20-8
• Molecular Formula: C₄₂H₃₆N₂O₄
• Molecular Weight: 632.759
• Mol file: 896102-20-8.mol

Synonyms:4,4'-bis{[(2''-benzylaminoformyl)phenoxy]methyl}-1,1'-biphenyl

Chemical Property of 4,4'-bis{[(2''-benzylaminoformyl)phenoxy]methyl}-1,1'-biphenyl

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of 4,4'-bis{[(2''-benzylaminoformyl)phenoxy]methyl}-1,1'-biphenyl

There total 1 articles about 4,4'-bis{[(2''-benzylaminoformyl)phenoxy]methyl}-1,1'-biphenyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

4-4'-bis(bromomethyl)biphenyl (20248-86-6) + N-benzylsalicylamide (20919-36-2) → 4,4'-bis{[(2''-benzylaminoformyl)phenoxy]methyl}-1,1'-biphenyl (896102-20-8)

Guidance literature:

With potassium carbonate; In N,N-dimethyl-formamide; at 90 - 95 ℃; for 8h;

DOI:10.1016/j.saa.2005.07.062

Reference yield: 70.0%

4,4'-bis{[(2''-benzylaminoformyl)phenoxy]methyl}-1,1'-biphenyl (896102-20-8) + terbium(III) nitrate hexahydrate → 2Tb(3+)*6NO3(1-)*3(C6H5CH2NHCOC6H4OCH2C6H4)2*2H2O=Tb2(NO3)6((C6H5CH2NHCOC6H4OCH2C6H4)2)3(H2O)2

Guidance literature:

In chloroform; ethyl acetate; am ethyl acetate soln. of Ln(NO3)3*6H2O was added dropwise to a soln. ofbiphenyl-compound in CHCl3, the mixt. was stirred at room temp. for 8 h; ppt. was filtered, washed with ethyl acetate and chloroform, dried in vac. over P4O10 for 48 h; elem. anal.;

DOI:10.1016/j.saa.2005.07.062

Reference yield: 70.0%

4,4'-bis{[(2''-benzylaminoformyl)phenoxy]methyl}-1,1'-biphenyl (896102-20-8) + holmium(III) nitrate hexahydrate → 2Ho(3+)*6NO3(1-)*3(C6H5CH2NHCOC6H4OCH2C6H4)2*2H2O=Ho2(NO3)6((C6H5CH2NHCOC6H4OCH2C6H4)2)3(H2O)2

Guidance literature:

In chloroform; ethyl acetate; am ethyl acetate soln. of Ln(NO3)3*6H2O was added dropwise to a soln. ofbiphenyl-compound in CHCl3, the mixt. was stirred at room temp. for 8 h; ppt. was filtered, washed with ethyl acetate and chloroform, dried in vac. over P4O10 for 48 h; elem. anal.;

DOI:10.1016/j.saa.2005.07.062

upstream raw materials:

4-4'-bis(bromomethyl)biphenyl

N-benzylsalicylamide