(1S,5R,Z)-5-{3-[2-benzyloxy-4-(tert-butyldiphenylsilanyloxy)phenyl]-1-[(2-methoxyethoxy)methoxy]-2-propen-2-yl}-2-methyl-1-(2-methyl-2-propen-1-yl)-2-cyclohexenol

Base Information

Chemical Name:(1S,5R,Z)-5-{3-[2-benzyloxy-4-(tert-butyldiphenylsilanyloxy)phenyl]-1-[(2-methoxyethoxy)methoxy]-2-propen-2-yl}-2-methyl-1-(2-methyl-2-propen-1-yl)-2-cyclohexenol
CAS No.:1115266-87-9
Molecular Formula:C₄₇H₅₈O₆Si
Molecular Weight:747.059
Hs Code.:

(1S,5R,Z)-5-{3-[2-benzyloxy-4-(tert-butyldiphenylsilanyloxy)phenyl]-1-[(2-methoxyethoxy)methoxy]-2-propen-2-yl}-2-methyl-1-(2-methyl-2-propen-1-yl)-2-cyclohexenol

Synonyms:(1S,5R,Z)-5-{3-[2-benzyloxy-4-(tert-butyldiphenylsilanyloxy)phenyl]-1-[(2-methoxyethoxy)methoxy]-2-propen-2-yl}-2-methyl-1-(2-methyl-2-propen-1-yl)-2-cyclohexenol

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Chemical Property of (1S,5R,Z)-5-{3-[2-benzyloxy-4-(tert-butyldiphenylsilanyloxy)phenyl]-1-[(2-methoxyethoxy)methoxy]-2-propen-2-yl}-2-methyl-1-(2-methyl-2-propen-1-yl)-2-cyclohexenol

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Technology Process of (1S,5R,Z)-5-{3-[2-benzyloxy-4-(tert-butyldiphenylsilanyloxy)phenyl]-1-[(2-methoxyethoxy)methoxy]-2-propen-2-yl}-2-methyl-1-(2-methyl-2-propen-1-yl)-2-cyclohexenol

There total 1 articles about (1S,5R,Z)-5-{3-[2-benzyloxy-4-(tert-butyldiphenylsilanyloxy)phenyl]-1-[(2-methoxyethoxy)methoxy]-2-propen-2-yl}-2-methyl-1-(2-methyl-2-propen-1-yl)-2-cyclohexenol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 948582-58-9
(R,Z)-5-{3-[2-benzyloxy-4-(tert-butyldiphenylsilyloxy)phenyl]-1-(2-methoxyethoxy)methoxy-2-propen-2-yl}-2-methylcyclohex-2-en-1-one

: 5674-01-1
2-methylallylmagnesium chloride

: 1115266-87-9
(1S,5R,Z)-5-{3-[2-benzyloxy-4-(tert-butyldiphenylsilanyloxy)phenyl]-1-[(2-methoxyethoxy)methoxy]-2-propen-2-yl}-2-methyl-1-(2-methyl-2-propen-1-yl)-2-cyclohexenol

Guidance literature:: (R,Z)-5-{3-[2-benzyloxy-4-(tert-butyldiphenylsilyloxy)phenyl]-1-(2-methoxyethoxy)methoxy-2-propen-2-yl}-2-methylcyclohex-2-en-1-one; 2-methylallylmagnesium chloride; In diethyl ether; at -78 ℃; for 0.5h; Inert atmosphere;

With ammonium chloride; In diethyl ether; water;
DOI:10.1016/j.tet.2008.11.055

Reference yield: 83.0%

: 75-77-4
chloro-trimethyl-silane

: 1115266-87-9
(1S,5R,Z)-5-{3-[2-benzyloxy-4-(tert-butyldiphenylsilanyloxy)phenyl]-1-[(2-methoxyethoxy)methoxy]-2-propen-2-yl}-2-methyl-1-(2-methyl-2-propen-1-yl)-2-cyclohexenol

: 1115266-88-0
(4R,6S,Z)-4-{3-[2-benzyloxy-4-(tert-butyldiphenylsilanyloxy)phenyl]-1-[(2-methoxyethoxy)methoxy]-2-propen-2-yl}-1-methyl-6-(2-methyl-2-propen-1-yl)-6-trimethylsilanyloxycyclohexene

Guidance literature:: With 1H-imidazole; In N,N-dimethyl-formamide; at 20 ℃; for 1h;
DOI:10.1016/j.tet.2008.11.055

Reference yield: 26.0%

: 1115266-87-9
(1S,5R,Z)-5-{3-[2-benzyloxy-4-(tert-butyldiphenylsilanyloxy)phenyl]-1-[(2-methoxyethoxy)methoxy]-2-propen-2-yl}-2-methyl-1-(2-methyl-2-propen-1-yl)-2-cyclohexenol

: 1115266-91-5
(1S,5R,Z)-5-{3-[2-benzyloxy-4-hydroxyphenyl]-1-[(2-methoxyethoxy)methoxy]2-propen-2-yl}-2-methyl-1-(2-methyl-2-propen-1-yl)-2-cyclohexenol

Guidance literature:: (1S,5R,Z)-5-{3-[2-benzyloxy-4-(tert-butyldiphenylsilanyloxy)phenyl]-1-[(2-methoxyethoxy)methoxy]-2-propen-2-yl}-2-methyl-1-(2-methyl-2-propen-1-yl)-2-cyclohexenol; With 18-crown-6 ether; potassium hexamethylsilazane; In hexane; toluene; at -78 ℃; for 21.5h; Reflux;

With ammonium chloride; In hexane; water; toluene; at 20 ℃;
DOI:10.1016/j.tet.2008.11.055