2-(2'-tert-butyldimethylsilyloxy-ethan-1'-yl)-cyclohex-6-en-1-yl-trifluoromethanesulphonate

Base Information

Chemical Name:2-(2'-tert-butyldimethylsilyloxy-ethan-1'-yl)-cyclohex-6-en-1-yl-trifluoromethanesulphonate
CAS No.:944382-60-9
Molecular Formula:C₁₅H₂₇F₃O₄SSi
Molecular Weight:388.524
Hs Code.:

Synonyms:2-(2'-tert-butyldimethylsilyloxy-ethan-1'-yl)-cyclohex-6-en-1-yl-trifluoromethanesulphonate

Suppliers and Price of 2-(2'-tert-butyldimethylsilyloxy-ethan-1'-yl)-cyclohex-6-en-1-yl-trifluoromethanesulphonate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 2-(2'-tert-butyldimethylsilyloxy-ethan-1'-yl)-cyclohex-6-en-1-yl-trifluoromethanesulphonate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 2-(2'-tert-butyldimethylsilyloxy-ethan-1'-yl)-cyclohex-6-en-1-yl-trifluoromethanesulphonate

There total 3 articles about 2-(2'-tert-butyldimethylsilyloxy-ethan-1'-yl)-cyclohex-6-en-1-yl-trifluoromethanesulphonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 145386-47-6
2-(2'-tert-butyldimethylsilyloxy-ethan-1'-yl)-cyclohexan-1-one

: 37595-74-7
N,N-phenylbistrifluoromethane-sulfonimide

: 944382-60-9
2-(2'-tert-butyldimethylsilyloxy-ethan-1'-yl)-cyclohex-6-en-1-yl-trifluoromethanesulphonate

Guidance literature:: 2-(2'-tert-butyldimethylsilyloxy-ethan-1'-yl)-cyclohexan-1-one; With n-butyllithium; diisopropylamine; In tetrahydrofuran; at -78 - 20 ℃; for 2h;

N,N-phenylbistrifluoromethane-sulfonimide; In tetrahydrofuran; at -78 - 0 ℃; for 3h; Further stages.;
DOI:10.1039/b703373g

Reference yield:

: 10198-27-3
2-(2-hydroxyethyl)-cyclohexan-1-one

: 944382-60-9
2-(2'-tert-butyldimethylsilyloxy-ethan-1'-yl)-cyclohex-6-en-1-yl-trifluoromethanesulphonate

Guidance literature:: Multi-step reaction with 2 steps

1.1: 0.85 g / triethylamine; 4-dimethylaminopyridine / CH₂Cl₂ / 16 h / 20 °C

2.1: diisopropylamine; n-butyllithium / tetrahydrofuran / 2 h / -78 - 20 °C

2.2: 99 percent / tetrahydrofuran / 3 h / -78 - 0 °C

With dmap; n-butyllithium; triethylamine; diisopropylamine; In tetrahydrofuran; dichloromethane;
DOI:10.1039/b703373g

Reference yield:

: 76593-65-2
1-(Hexahydro-benzofuran-7a-yl)-pyrrolidine

: 944382-60-9
2-(2'-tert-butyldimethylsilyloxy-ethan-1'-yl)-cyclohex-6-en-1-yl-trifluoromethanesulphonate

Guidance literature:: Multi-step reaction with 3 steps

1.1: aq. hydrochloric acid / 5 h / Heating

2.1: 0.85 g / triethylamine; 4-dimethylaminopyridine / CH₂Cl₂ / 16 h / 20 °C

3.1: diisopropylamine; n-butyllithium / tetrahydrofuran / 2 h / -78 - 20 °C

3.2: 99 percent / tetrahydrofuran / 3 h / -78 - 0 °C

With hydrogenchloride; dmap; n-butyllithium; triethylamine; diisopropylamine; In tetrahydrofuran; dichloromethane;
DOI:10.1039/b703373g