1,1'-bis(2-dicyclohexylphosphinoethoxy)ferrocene

Base Information

Chemical Name:1,1'-bis(2-dicyclohexylphosphinoethoxy)ferrocene
CAS No.:186806-38-2
Molecular Formula:C₃₈H₆₀FeO₂P₂
Molecular Weight:666.688
Hs Code.:

Synonyms:1,1'-bis(2-dicyclohexylphosphinoethoxy)ferrocene

Suppliers and Price of 1,1'-bis(2-dicyclohexylphosphinoethoxy)ferrocene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 1,1'-bis(2-dicyclohexylphosphinoethoxy)ferrocene

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 1,1'-bis(2-dicyclohexylphosphinoethoxy)ferrocene

There total 1 articles about 1,1'-bis(2-dicyclohexylphosphinoethoxy)ferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

: 86968-34-5
bis(2-chloroethoxy)ferrocene

: 829-84-5
dicyclohexylphosphane

: 186806-38-2
1,1'-bis(2-dicyclohexylphosphinoethoxy)ferrocene

Guidance literature:: With BuLi; In tetrahydrofuran; pentane; inert atmosphere, addn. of pentane soln. of BuLi to THF soln. of phosphine (0°C), after 50 min the soln. was added to THF soln. of ferrocene compound (0°C), (0°C, 8 h), slow warming to room temp.; evapn. onto aluminia (predried (0.02 mm Hg), column chromy. (Et2O/pentane (1/4), glove box); elem. anal.;
DOI:10.1021/ja963008a

Reference yield: 55.0%

: 14104-20-2
silver tetrafluoroborate

: [Rh(μ-Cl)(η(2)-C8H14)2]x

: 186806-38-2
1,1'-bis(2-dicyclohexylphosphinoethoxy)ferrocene

: 186806-45-1
[rhodium(I) 1,1'-bis(2-dicyclohexylphosphinoethoxy)ferrocene] tetrafluoroborate

Guidance literature:: In tetrahydrofuran; inert atmosphere, stirring of rhodium complex with AgBF4 (25°C, 1 h), filtration, diln., cooling (-40°C), addn. of soln. of ferrocene compound, stirring (1 h); removement of solvent (vacuum), pptn. (hexane);
DOI:10.1021/ja963008a

Reference yield:

: 21797-13-7
tetrakis(acetonitrile)palladium(II) tetrafluoroborate

: 186806-38-2
1,1'-bis(2-dicyclohexylphosphinoethoxy)ferrocene

: palladium(II) 1,1'-bis(2-dicyclohexylphosphinoethoxy)ferrocene bis(tetrafluoroborate)

Guidance literature:: In acetone; inert atmosphere, stirring of palladium complex with ferrocene compound(-50°C, 40 min), warming to room temp.; removement of solvent, spectroscopic yield >95%;
DOI:10.1021/ja963008a